Effects of bromide on the formation of THMs and HAAs

被引:148
作者
Chang, EE
Lin, YP
Chiang, PC
机构
[1] Taipei Med Coll, Dept Biochem, Taipei 105, Taiwan
[2] Natl Taiwan Univ, Grad Inst Environm Engn, Taipei 10764, Taiwan
关键词
bromide; chlorination; trihalomethanes; haloacetic acids;
D O I
10.1016/S0045-6535(00)00210-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The role of bromide in the formation and speciation of disinfection by-products (DBPs) during chlorination was investigated. The molal ratio of applied chlorine to bromide is an important factor in the formation and speciation of trihalomethanes (THMs) and halogenacetic acids (HAAs). A good relationship exists between the molar fractions of THMs and the bromide incorporation factor. The halogen substitution ability of HOBr and HOCl during the formation of THMs and HAAs can be determined based on probability theory. The formation of HAAs, and their respective concentrations. can also be estimated through use of the developed model. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1029 / 1034
页数:6
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