Isolation of two geometrical isomers of bis(mu-acetato)(mu-oxo)diiron(III) complexes with tridentate ligands and their activities for functionalization of cyclohexane in the presence of hydrogen peroxide

被引：12

作者：

Ito, S

Okuno, T

Matsushima, H

Tokii, T

Nishida, Y

机构：

[1] YAMAGATA UNIV, FAC SCI, DEPT CHEM, YAMAGATA 990, JAPAN

[2] SAGA UNIV, FAC SCI & ENGN, DEPT CHEM, SAGA 840, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 21期

关键词：

D O I：

10.1039/dt9960004037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two geometrical isomers of bis(mu-acetato)(mu-oxo)diiron(III) complexes with tridentate ligands were isolated and characterized by X-ray crystallography and their activities for cyclohexane functionalization in the presence of hydrogen peroxide examined.

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页码：4037 / 4039

页数：3

相关论文

共 16 条

[1] (MU-OXO)BIS(MU-ACETATO)BIS(TRI-1-PYRAZOLYLBORATO)DIIRON-(III), [(HBPZ3)FEO(CH3CO2)2FE(HBPZ3)] - MODEL FOR THE BINUCLEAR IRON CENTER OF HEMERYTHRIN [J].

ARMSTRONG, WH ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (14) :4837-4838

[2] REACTIONS OF NONHEME IRON(II) CENTERS WITH DIOXYGEN IN BIOLOGY AND CHEMISTRY [J].

FEIG, AL ;

LIPPARD, SJ .

CHEMICAL REVIEWS, 1994, 94 (03) :759-805

[3] Formation and reactivity of a peroxide adduct of iron(III) complexes containing substituted phenol derivatives [J].

Ito, S ;

Suzuki, M ;

Kobayashi, T ;

Itoh, H ;

Harada, A ;

Ohba, S ;

Nishida, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (12) :2579-2580

[4]

Johnson C. K., 1976, ORNL5138 ORTEP

[5] 8-hydroxy-2'-deoxyguanosine formation and DNA damage induced by a dinuclear manganese(iv) complex and hydrogen peroxide [J].

Kobayashi, T ;

Tsuchiya, K ;

Nishida, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (11) :2391-2392

[6] MU-OXO-BRIDGED DIIRON(III) COMPLEXES AND H2O2 - MONOOXYGENASE-LIKE AND CATALASE-LIKE ACTIVITIES [J].

MENAGE, S ;

VINCENT, JM ;

LAMBEAUX, C ;

FONTECAVE, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (14) :2081-2084

[7] ALKANE OXIDATION CATALYZED BY MU-OXO-BRIDGED DIFFERIC COMPLEXES - A STRUCTURE-REACTIVITY CORRELATION STUDY [J].

MENAGE, S ;

VINCENT, JM ;

LAMBEAUX, C ;

CHOTTARD, G ;

GRAND, A ;

FONTECAVE, M .

INORGANIC CHEMISTRY, 1993, 32 (22) :4766-4773

[8]

*MOL STRUCT CORP, 1985, TEXSAN TEXRA STRUCT

[9] SYNTHESIS AND PROPERTIES OF DINUCLEAR IRON OXO COMPLEXES WITH TETRADENTATE TRIPODAL LIGANDS [J].

NISHIDA, Y ;

NASU, M ;

TOKII, T .

INORGANICA CHIMICA ACTA, 1990, 169 (02) :143-145

[10]

NISHIDA Y, 1992, Z NATURFORSCH B, V47, P115