Effect of rare earth addition on super-hydrophilic property of TiO2/SiO2 composite film

被引:54
作者
Guan, KS [1 ]
Yin, YS
机构
[1] E China Univ Sci & Technol, Res Inst Proc Equipment, Shanghai 200237, Peoples R China
[2] Ocean Univ China, Sch Mat Sci & Engn, Qingdao 266003, Peoples R China
关键词
TiO2/SiO2 composite films; rare earth oxide; super-hydrophilic property;
D O I
10.1016/j.matchemphys.2004.01.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effects of CeO2 or/and La2O3 addition on photo-generated hydrophilicity of TiO2/SiO2 film were investigated in this paper with the testing of X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible spectroscopy (UV-vis) and scanning electron microscopy (SEM). It is found that appropriate amount of CeO2 or/and La2O3 is effective on the super-hydrophilic property of TiO2 because of the increase of oxygen vacancies. The super-hydrophilic property of the composite film becomes better during UV irradiation and it can maintain for a long time in the dark with the synergetic effect of rare earth oxides and SiO2. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:10 / 15
页数:6
相关论文
共 25 条
[1]  
CARLA GJ, 2003, J PHOTOCH PHOTOBIO A, V155, P215
[2]   Photocatalytic degradation of imazaquin in an aqueous suspension of titanium dioxide [J].
Garcia, JC ;
Takashima, K .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 155 (1-3) :215-222
[3]  
Guan KS, 2004, T NONFERR METAL SOC, V14, P251
[4]   Enhanced effect and mechanism of SiO2 addition in super-hydrophilic property of TiO2 films [J].
Guan, KS ;
Lu, BJ ;
Yin, YS .
SURFACE & COATINGS TECHNOLOGY, 2003, 173 (2-3) :219-223
[5]   Development of hydrophilic outside mirror coated with titania photocatalyst [J].
Hata, S ;
Kai, Y ;
Yamanaka, I ;
Oosaki, H ;
Hirota, K ;
Yamazaki, S .
JSAE REVIEW, 2000, 21 (01) :97-102
[6]   ACIDIC PROPERTIES OF TIO2-SIO2 AND ITS CATALYTIC ACTIVITIES FOR AMINATION OF PHENOL, HYDRATION OF ETHYLENE AND ISOMERIZATION OF BUTENE [J].
ITOH, M ;
HATTORI, H ;
TANABE, K .
JOURNAL OF CATALYSIS, 1974, 35 (02) :225-231
[7]  
Kai-shu G., 2004, T NONFERR METAL SOC, V14, P251
[8]  
KAUSHU G, 2003, SURF COAT TECH, V173, P219
[9]   An investigation on photocatalytic activities of mixed TiO2-rare earth oxides for the oxidation of acetone in air [J].
Lin, J ;
Yu, JC .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1998, 116 (01) :63-67
[10]  
LIU J, 1998, J PHOTOCH PHOTOBIO A, V116, P63