Self-assembly of 1:2 inclusion complexes between a metallocyple host and dihydroxyaromatic guests:: A redox controlled complexation process

被引：43

作者：

Blanco, Victor ^{[1
]}

Chas, Marcos ^{[1
]}

Abella, Dolores ^{[1
]}

Pia, Elena ^{[1
]}

Platas-Iglesias, Carlos ^{[1
]}

Peinador, Carlos ^{[1
]}

Quintela, Jose M. ^{[1
]}

机构：

[1] Univ A Coruna, Fac Ciencias, Dept Quim Fundamental, La Coruna 15071, Spain

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 03期

关键词：

DIELS-ALDER; PD-II; LIGAND; METALLOMACROCYCLES; SPECTROSCOPY; CHEMISTRY; SELECTION; CAPSULE; DESIGN;

D O I：

10.1021/ol702701t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new 1:2 inclusion complexes were prepared by self-assembly of three components: a ligand based on 4,4'-bipyridinium, a square-planar Pd complex, and a dihydroxyaromatic guest (hydroquinone or 1,5-dihydroxynaphthalene) in a 2:2:2 ratio. Their X-ray structural analyses revealed that the complexes are stabilized by pi-pi stacking and [C-H center dot center dot center dot pi] interactions.

引用

页码：409 / 412

页数：4

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