Synthesis of nanostructured mesoporous silica materials containing manganese

被引：41

作者：

Wang, LZ ^{[1
]}

Shi, JL ^{[1
]}

Yu, J ^{[1
]}

Yan, DS ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

NANOSTRUCTURED MATERIALS | 1998年 / 10卷 / 08期

关键词：

D O I：

10.1016/S0965-9773(99)00009-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The nanostructured mesoporous silica MCM-41 materials with different amounts of manganese have been synthesized under basic conditions at room temperature. The characteristics of the Mn-containing mesoporous samples were investigated by XRD, FTIR, Nz adsorption, Si-29 MASNMR and HREM techniques. Tt has been shown that the (100) peak intensity of XRD patterns became weakened and the specific surface area of materials decreased monotonously with the increase of Mn contents. FTIR results indicated that Mn ions could be incorporated into the Si-O framework and lead to the vibration of Si-O-Mn bond. Si-29 MASNMR results suggested that the values of [SiO4] tetrahedra in the framework decreased with the increase of Mn ions addition, resulting in the decrease of Q(4) / Q(3) ratio. It could be seen from HREM images that nanostructured framework of Mn-modified mesoporous silica was distorted, and lamellar structure co-existed with hexagonal structure in some area. (C)1999 Acta Metallurgica Inc.

引用

页码：1289 / 1299

页数：11

共 21 条

[1]

[Anonymous], CHEM MATER

[2]

Boccuti M. R., 1989, STUD SURF SCI CATAL, V48, P133, DOI [10.1016/s0167-2991(08)60677-1, DOI 10.1016/S0167-2991(08)60677-1]

[3] STUDIES ON MESOPOROUS MATERIALS .1. SYNTHESIS AND CHARACTERIZATION OF MCM-41 [J].