Homogeneity range of ScMnO3 in air

被引：4

作者：

Golikov, YV ^{[1
]}

Balakirev, VF ^{[1
]}

Titova, SG ^{[1
]}

Fedorova, OM ^{[1
]}

Antonov, AV ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Met, Ural Div, Ekaterinburg 620016, Russia

来源：

INORGANIC MATERIALS | 2005年 / 41卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Inorganic Chemistry; Solid Solution; Phase Boundary; Homogeneity Range; Sc2O3;

D O I：

10.1007/s10789-005-0161-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

SccMn2-cO3 (0.9 <= c <= 1.1) samples were prepared by reacting Sc2O3 and Mn2O3 in air between 800 and 1350 degrees C and were characterized by x-ray diffraction. The results were used to determine the homogeneity range of ScMnO3. The Mn- and Sc-rich phase boundaries of ScMnO3 are at c similar or equal to 0.975 (800-1250 degrees C) and c similar or equal to 1.025 (800-1200 degrees C), respectively. At higher temperatures, the homogeneity range narrows down. At 1305 +/- 5 degrees C, stoichiometric ScMnO3 dissociates to form Sc2O3- and Mn3O4-based solid solutions.

引用

页码：524 / 525

页数：2