The solvent effect on the Diels-Alder reaction in ionic liquids: multiparameter linear solvation energy relationships and theoretical analysis

被引：104

作者：

Chiappe, Cinzia ^{[1
]}

Malvaldi, Marco ^{[1
]}

Pomelli, Christian Silvio ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 08期

关键词：

MOLECULAR-ORBITAL INTERACTION; PERCHLORATE-DIETHYL-ETHER; NANOSTRUCTURAL ORGANIZATION; TRANSITION-STATES; RATE ACCELERATION; CYCLOPENTADIENE; ACTIVATION; WATER; RATIONALIZATION; ENHANCEMENT;

D O I：

10.1039/c0gc00074d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review illustrates how ionic liquid properties can affect Die Is-Alder reactions The mechanisms by which ionic solvents enhance the rate and selectivity of the reaction are discussed on the basis of correlation studies using empirical parameters and theoretical calculations

引用

收藏

页码：1330 / 1339

页数：10

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