Hydroformylation in reverse micellar systems

被引：30

作者：

Van Vyve, F ^{[1
]}

Renken, A ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, EPFL, Lausanne, Switzerland

来源：

CATALYSIS TODAY | 1999年 / 48卷 / 1-4期

关键词：

microemulsion; hydroformulation; inverse micelles; water-soluble rhodium complex;

D O I：

10.1016/S0920-5861(98)00378-2

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Different micellar systems are characterized. Hydroformylation reactions are carried out in the most appropriate ones and are compared with hydroformylations in a non-micellar system. Reaction rates and selectivities for aldehydes are higher than the micelles. In addition to this, olefins between C-6 and C-16 are successfully hydroformylated in the micellar system, whereas Cg is the highest olefin that can be hydroformylated without micelles. The behavior of the reaction in the micellar system is very sensitive to the initial composition and reaction conditions. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：237 / 243

页数：7