The chirality, porosity, and ferromagnetism of a 3D nickel glutarate with intersecting 20-membered ring channels

被引：182

作者：

Guillou, N

Livage, C

Drillon, M

Férey, G

机构：

[1] Univ Versailles St Quentin Yvelines, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

[2] Inst Phys & Chim Mat Strasbourg, F-67037 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 43期

关键词：

chirality; ferromagnetism; microporous materials; nickel; O ligands;

D O I：

10.1002/anie.200352520

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new dimension to nickel structures: A three-dimensional nickel glutarate, [Ni20{(C5H6O4)20(H 2O)8}]·40 H2O, has been prepared under hydrothermal conditions. Its structure, solved from X-ray powder diffraction, is constructed from interconnected 20-rings, which form a remarkable open network of crossing channels (see picture). It is porous, and exhibits a ferromagnetic long-range ordering below 4 K.

引用

页码：5314 / 5317

页数：4

共 38 条

[1] EXPO:: a program for full powder pattern decomposition and crystal structure solution
Altomare, A
Burla, MC
Camalli, M
Carrozzini, B
Cascarano, GL
Giacovazzo, C
Guagliardi, A
Moliterni, AGG
Polidori, G
Rizzi, R
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 339 - 340
[2] EXTRA: A program for extracting structure factor amplitudes from powder diffraction data.
Altomare, A
Burla, MC
Cascarano, G
Giacovazzo, G
Guagliardi, A
Moliterni, AGG
Polidori, G
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1995, 28 : 842 - 846
[3] SIR97:: a new tool for crystal structure determination and refinement
Altomare, A
Burla, MC
Camalli, M
Cascarano, GL
Giacovazzo, C
Guagliardi, A
Moliterni, AGG
Polidori, G
Spagna, R
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 115 - 119
[4] INDEXING OF POWDER DIFFRACTION PATTERNS FOR LOW-SYMMETRY LATTICES BY THE SUCCESSIVE DICHOTOMY METHOD
BOULTIF, A
LOUER, D
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 (pt 6) : 987 - 993
[5] BOWDEN TA, 2003, J CHEM SOC DA, V5, P936
[6] Carvajal J. R., 1990, SAT M POWD DIFFR 15, P127
[7] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n
Chui, SSY
Lo, SMF
Charmant, JPH
Orpen, AG
Williams, ID
[J]. SCIENCE, 1999, 283 (5405) : 1148 - 1150
[8] Highly porous and stable metal-organic frameworks: Structure design and sorption properties
Eddaoudi, M
Li, HL
Yaghi, OM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) : 1391 - 1397
[9] New materials in hydrothermal synthesis
Feng, SH
Xu, RR
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) : 239 - 247
[10] Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry
Férey, G
[J]. CHEMISTRY OF MATERIALS, 2001, 13 (10) : 3084 - 3098

← 1 2 3 4 →