Synthesis of nearly monodisperse polystyrene-polypeptide block copolymers via polymerisation of N-carboxyanhydrides

被引：255

作者：

Dimitrov, I ^{[1
]}

Schlaad, H ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Golm, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 23期

关键词：

D O I：

10.1039/b308990h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Primary amine hydrochlorides promote a well-controlled ring-opening polymerisation of Z-L-lysine-N-carboxyanhydride in DMF at 40-80degreesC; the polystyrene-poly(Z-L-lysine) block copolymers synthesised exhibit a very narrow molecular weight distribution, close to a Poisson distribution.

引用

页码：2944 / 2945

页数：2

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