Structural analysis of bio-oils from pyrolysis and steam pyrolysis of cottonseed cake

被引:70
作者
Özbay, N [1 ]
Pütün, AE [1 ]
Pütün, E [1 ]
机构
[1] Anadolu Univ, Fac Engn & Architecture, Dept Chem Engn, TR-26470 Eskisehir, Turkey
关键词
biomass; cottonseed cake; pyrolysis; instrumental analysis;
D O I
10.1016/S0165-2370(00)00161-3
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Structural analysis and the effect of the water vapour on the structure of the products obtained by low temperature thermal destruction of biomass at atmospheric pressure has been investigated. The liquid products were fractionated into pentane solubles and insolubles (Asphaltenes). Pentane solubles were then solvent fractionated into pentane, toluene, ether and methanol subfractions by fractionated column chromatograpy. The aliphatic subfractions of the oils were then analysed by capillary column gas-liquid chromatography and GC/MS. For further structural analysis, the pyrolysis oils and aromatic and polar subfractions were conducted using FTIR and H-1-NMR spectra. (C) 2001 Elsevier Science B,V. All rights reserved.
引用
收藏
页码:89 / 101
页数:13
相关论文
共 19 条
[1]  
ALHARFI K, 1999, J ANAL APPL PYROL, V48, P65
[2]  
BARTLE KD, 1978, ANAL METHODS COAL CO, P223
[3]  
DESBENE PL, 1991, BIOMASS PYROLYSIS LI
[4]  
EISA MH, 1994, 231 WORLD BANK, P112
[5]   EFFECT OF LIGNITE ADDITION AND STEAM ON THE PYROLYSIS OF TURKISH OIL SHALES [J].
EKINCI, E ;
CITIROGLU, M ;
PUTUN, E ;
LOVE, GD ;
LAFFERTY, CJ ;
SNAPE, CE .
FUEL, 1992, 71 (12) :1511-1514
[6]  
Elliott D. C., 1988, ACS S SERIES, V376
[7]  
HEINZE R, 1943, OEL KOHLE, V39, P973
[8]   EFFECT OF WATER-VAPOR ON THE PYROLYSIS OF SOLID FUELS .1. EFFECT OF WATER-VAPOR DURING THE PYROLYSIS OF SOLID FUELS ON THE YIELD AND COMPOSITION OF THE LIQUID PRODUCTS [J].
MINKOVA, V ;
RAZVIGOROVA, M ;
GORANOVA, M ;
LJUTZKANOV, L ;
ANGELOVA, G .
FUEL, 1991, 70 (06) :713-719
[9]   HYDROCARBONS FROM EUPHORBIA-LATHYRIS [J].
NEMETHY, EK ;
OTVOS, JW ;
CALVIN, M .
PURE AND APPLIED CHEMISTRY, 1981, 53 (06) :1101-1108
[10]  
OZBAY N, 1998, THESIS OSMANGAZI U E