High reaction activity of nitrogen-doped carbon nanotubes toward the electrooxidation of nitric oxide

被引：39

作者：

Xu, Xuan ^{[1
]}

Yang, Lijun ^{[2
]}

Jiang, Shujuan ^{[2
]}

Hu, Zheng ^{[2
]}

Liu, Songqin ^{[1
]}

机构：

[1] SE Univ Jiangning, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 25期

基金：

中国国家自然科学基金;

关键词：

CNX NANOTUBES; ELECTRODES; ELECTROCATALYSIS; NANOPARTICLES; REDUCTION; OXIDATION; GRAPHITE; SENSORS; ENDS;

D O I：

10.1039/c1cc11611h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon nanotubes doped with N (NCNTs) enable 1.5 times faster electron-transfer kinetics for the oxidation of NO compared to pristine carbon nanotubes (CNTs), which may be due to the low adsorption energy for a NO on pyridinic NCNT(5,5) allowing NO to lose electrons readily and facilitate the following oxidation to nitrate.

引用

页码：7137 / 7139

页数：3

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