Preparation of the N,N,N',N'-tetramethylethylenediamine complex of hydridozinc chloride. Reactions of zinc hydrides with some organic substrates

被引：13

作者：

Bell, NA

Kassyk, AL

机构：

来源：

INORGANICA CHIMICA ACTA | 1996年 / 250卷 / 1-2期

关键词：

zinc complexes; hydride complexes;

D O I：

10.1016/S0020-1693(96)05250-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc hydride and zinc chloride react together in THF in the presence of TMEDA to form the title compound. The reactions of a range of zinc hydrides with a variety of organic substrates are described.

引用

页码：345 / 349

页数：5

共 32 条

[1] PREPARATION AND CHARACTERIZATION OF ALKOXY(AROXY)MAGNESIUM HYDRIDES [J].

ASHBY, EC ;

GOEL, AB .

INORGANIC CHEMISTRY, 1979, 18 (05) :1306-1311

[2] EVIDENCE FOR AN ELECTRON-TRANSFER MECHANISM IN THE REDUCTION OF KETONES BY MAIN-GROUP METAL-HYDRIDES [J].

ASHBY, EC ;

GOEL, AB ;

DEPRIEST, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (26) :7779-7780

[3] PREPARATION AND CHARACTERIZATION OF (DIALKYLAMINO)-MAGNESIUM AND (DIARYLAMINO)MAGNESIUM HYDRIDES [J].

ASHBY, EC ;

GOEL, AB .

INORGANIC CHEMISTRY, 1978, 17 (07) :1862-1866

[4] NEW AND CONVENIENT METHOD FOR PREPARATION OF COMPLEX METAL HYDRIDES OF GROUP-II METALS - SYNTHESIS OF COMPLEX METAL HYDRIDES OF ZINC [J].

ASHBY, EC ;

WATKINS, JJ .

INORGANIC CHEMISTRY, 1973, 12 (11) :2493-2503

[5] PREPARATION OF NEW COMPLEX METAL HYDRIDES - POTASSIUM TETRAHYDROZINCATE AND SODIUM TETRAHYDROZINCATE [J].

ASHBY, EC ;

BEACH, RG .

INORGANIC CHEMISTRY, 1971, 10 (11) :2486-&

[6] NATURE OF ALKYL-HYDROGEN EXCHANGE-REACTIONS INVOLVING ALUMINUM AND ZINC .5. REACTIONS OF DIPHENYLZINC WITH LITHIUM ALUMINUM-HYDRIDE IN DIETHYL-ETHER AND TETRAHYDROFURAN - PREPARATION OF PHZN2H3 [J].

ASHBY, EC ;

GOEL, AB .

INORGANIC CHEMISTRY, 1981, 20 (04) :1096-1101

[7] PREPARATION OF HMGX COMPOUNDS AND THEIR REACTIONS WITH ALANE AND BORANE IN TETRAHYDROFURAN [J].

ASHBY, EC ;

GOEL, AB .

INORGANIC CHEMISTRY, 1977, 16 (11) :2941-2944

[8] REACTIONS OF ALUMINUM-HYDRIDE WITH GROUP 1B, 2A, AND 2B METAL-HALIDES [J].

ASHBY, EC ;

PRASAD, HS .

INORGANIC CHEMISTRY, 1975, 14 (07) :1608-1641

[9]

ASHBY EC, 1977, TETRAHEDRON LETT, V36, P3133

[10] TERMINAL ZINC-HYDROGEN BONDING - X-RAY AND NEUTRON-DIFFRACTION STUDIES OF 2-DIMETHYLAMINOETHYL(METHYL)AMINOZINC HYDRIDE DIMER [J].

BELL, NA ;

MOSELEY, PT ;

SHEARER, HMM ;

SPENCER, CB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (08) :359-360

← 1 2 3 4 →