A trinuclear gadolinium complex:: Structure and magnetic properties

被引:123
作者
Costes, JP
Dahan, F
Nicodème, F
机构
[1] Univ Toulouse 3, CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France
[2] Inst Natl Polytech Toulouse, F-31077 Toulouse, France
关键词
D O I
10.1021/ic0103704
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A genuine and original trinuclear gadolinium complex in which the three Gd centers are linked by three different phenolato or hydroxo bridges presents an antiferromagnetic interaction of 0.19cm(-1). This J value is among the largest ones found for interacting Gd centers.
引用
收藏
页码:5285 / +
页数:4
相关论文
共 22 条
  • [1] [Anonymous], 1992, INT TABLES CRYSTALLO, VC
  • [2] [Anonymous], SHELXS 97 PROGRAM CR
  • [3] EFFECT OF POLYETHER LIGANDS ON STABILITIES AND MASS-TRANSPORT PROPERTIES OF A SERIES OF GADOLINIUM(III) BETA-DIKETONATE COMPLEXES
    BAXTER, I
    DRAKE, SR
    HURSTHOUSE, MB
    MALIK, KMA
    MCALEESE, J
    OTWAY, DJ
    PLAKATOURAS, JC
    [J]. INORGANIC CHEMISTRY, 1995, 34 (06) : 1384 - 1394
  • [4] Chen XM, 1997, POLYHEDRON, V16, P4265
  • [5] Homo- (4f, 4f) and heterodimetallic (4f, 4f′) complexes.: The first structurally characterized example of a heterodimetallic (Yb, La) complex (1′).: Magnetic properties of 1′ and of a homodinuclear (Gd, Gd) analogue
    Costes, JP
    Dahan, F
    Dupuis, A
    Lagrave, S
    Laurent, JP
    [J]. INORGANIC CHEMISTRY, 1998, 37 (01) : 153 - 155
  • [6] Homodinuclear lanthanide complexes:: Ln2L3 (H2L equals tetradentate Schiff bases).: Magnetic properties (solid state) and spectroscopic studies (solution)
    Costes, JP
    Dupuis, A
    Laurent, JP
    [J]. INORGANICA CHIMICA ACTA, 1998, 268 (01) : 125 - 130
  • [7] FAIR CK, 1990, MOIEN STRUCTURE SOLU
  • [8] GUDEL HU, 1990, INORG CHEM, V29, P4081
  • [9] MONO-DINUCLEAR, HOMO-DINUCLEAR AND HETERO-DINUCLEAR LANTHANIDE(III) COMPLEXES WITH NEW ACYCLIC COMPARTMENTAL SCHIFF-BASES
    GUERRIERO, P
    TAMBURINI, S
    VIGATO, PA
    BENELLI, C
    [J]. INORGANICA CHIMICA ACTA, 1991, 189 (01) : 19 - 27
  • [10] Trinuclear lanthanoid complexes of 1,3,5-triamino-1,3,5-trideoxy-cis-inositol with a unique, sandwich-type cage structure
    Hedinger, R
    Ghisletta, M
    Hegetschweiler, K
    Tóth, E
    Merbach, AE
    Sessoli, R
    Gatteschi, D
    Gramlich, V
    [J]. INORGANIC CHEMISTRY, 1998, 37 (26) : 6698 - 6705