Anomalous transport properties of RFe4P12 (R = La, Ce, Pr, and Nd)

被引:223
作者
Sato, H [1 ]
Abe, Y [1 ]
Okada, H [1 ]
Matsuda, TD [1 ]
Abe, K [1 ]
Sugawara, H [1 ]
Aoki, Y [1 ]
机构
[1] Tokyo Metropolitan Univ, Dept Phys, Tokyo 1920397, Japan
关键词
D O I
10.1103/PhysRevB.62.15125
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have investigated the resistivity (rho), thermoelectric power (TEP), and Hall coefficient (RH) on high-quality single crystals of RFe4P12. TEP in CeFe4P12 is extremely large ( similar to 0.5 mV/K at 290 K)with a peak of similar to0.75 mV/K at around 65 K. The Hall mobility also shows a peak at similar to 65 K, suggesting carriers with heavy masses developed at lower temperatures related to the f-hybridized band. Both Pr and Nd systems exhibit an apparent increase of rho with decreasing temperature far above their magnetic transition temperatures. In the same temperature ranges, TEP exhibits unusually large absolute values of -50 muV/K for PrFe4P12 acid -15 muV/K for NdFe4P12, respectively. For PrFe4P12, such anomalous transport properties suggest an un usual ground state, possibly related to the quadrupolar Kondo effect.
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页码:15125 / 15130
页数:6
相关论文
共 33 条
[1]  
Chambers R. G., 1990, ELECT METALS SEMICON
[2]   THEORY FOR THE ANOMALOUS HALL CONSTANT OF MIXED-VALENCE SYSTEMS [J].
COLEMAN, P ;
ANDERSON, PW ;
RAMAKRISHNAN, TV .
PHYSICAL REVIEW LETTERS, 1985, 55 (04) :414-417
[3]   ELECTRICAL PROPERTIES OF N-TYPE GERMANIUM [J].
DEBYE, PP ;
CONWELL, EM .
PHYSICAL REVIEW, 1954, 93 (04) :693-706
[4]   THE PRESSURE-DEPENDENCE OF THE SUPERCONDUCTING TRANSITION-TEMPERATURE OF LAFE4P12, LARU4P12, LAOS4P12 [J].
DELONG, LE ;
MEISNER, GP .
SOLID STATE COMMUNICATIONS, 1985, 53 (02) :119-123
[5]   Intermediate valence in the filled skutterudite compound YbFe4Sb12 [J].
Dilley, NR ;
Freeman, EJ ;
Bauer, ED ;
Maple, MB .
PHYSICAL REVIEW B, 1998, 58 (10) :6287-6290
[6]   Optical properties of MFe4P12 filled skutterudites [J].
Dordevic, SV ;
Dilley, NR ;
Bauer, ED ;
Basov, DN ;
Maple, MB ;
Degiorgi, L .
PHYSICAL REVIEW B, 1999, 60 (16) :11321-11328
[7]  
Dugdale J.S., 1977, ELECT PROPERTIES MET
[8]   THEORY OF THE HALL-EFFECT IN HEAVY-FERMION COMPOUNDS [J].
FERT, A ;
LEVY, PM .
PHYSICAL REVIEW B, 1987, 36 (04) :1907-1916
[9]   Electronic structure and thermoelectric prospects of phosphide skutterudites [J].
Fornari, M ;
Singh, DJ .
PHYSICAL REVIEW B, 1999, 59 (15) :9722-9724
[10]  
FOURNIER JM, 1993, HDB PHYSICS CHEM RAR, V17, pCH115