Metal-Organic Framework Nanospheres with Well-Ordered Mesopores Synthesized in an Ionic Liquid/CO2/Surfactant System

被引:263
作者
Zhao, Yueju [1 ]
Zhang, Jianling [1 ]
Han, Buxing [1 ]
Song, Jinliang [1 ]
Li, Jianshen [1 ]
Wang, Qian [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Inst Chem, Beijing 100864, Peoples R China
基金
中国国家自然科学基金;
关键词
ionic liquids; mesoporous materials; metal-organic frameworks; nanoparticles; supercritical fluids; HYDROGEN STORAGE; COORDINATION COPOLYMER; CARBON-DIOXIDE; ADSORPTION; SEPARATION; CATALYSIS; POLYMERS; MIL-101; CENTERS; DESIGN;
D O I
10.1002/anie.201005314
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pores and pores: Metal-organic framework (MOF) nanospheres with long-range ordered mesopores, the walls of which are composed of microporous structure units, were synthesized in binary solvent systems of ionic liquid and supercritical CO2. The MOF nanostructure has many potential applications and its preparation could easily be applied to MOFs with other metal ions and ligands. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:636 / 639
页数:4
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