Protection of iron against corrosion using a polyaniline layer I. Polyaniline electrodeposit

被引：75

作者：

Bernard, MC ^{[1
]}

Joiret, S ^{[1
]}

Hugot-Le Goff, A ^{[1
]}

Phong, PV ^{[1
]}

机构：

[1] UPMC, CNRS, UPR 15, F-75252 Paris 05, France

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2001年 / 148卷 / 01期

关键词：

D O I：

10.1149/1.1344527

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Polyaniline (PANI) has been studied for some years in order to protect mild steels against corrosion in the absence of inorganic conversion layers. During the electropolymerization of PANI film, iron is passivated; the subsequent protection is dependent on the nature of this passive layer, and PANI acts as a stabilizer of this layer. The best conditions for PANI electrodeposition are discussed here, using a simple electrochemical test to characterize the passivity breakdown. (C) 2000 The Electrochemical Society. S0013-4651(00)04-070-2. All rights reserved.

引用

收藏

页码：B12 / B16

页数：5

相关论文

共 23 条

[1] Inhibition of corrosion of steels with the exploitation of conducting polymers [J].

Ahmad, N ;

MacDiarmid, AG .

SYNTHETIC METALS, 1996, 78 (02) :103-110

[2] XPS evidence of redox chemistry between cold rolled steel and polyaniline [J].

Beard, BC ;

Spellane, P .

CHEMISTRY OF MATERIALS, 1997, 9 (09) :1949-1953

[3] Combined impedance and Raman analysis in the study of corrosion protection of iron by polyaniline [J].

Bernard, MC ;

Deslouis, C ;

El Moustafid, T ;

Hugot-LeGoff, A ;

Joiret, S ;

Tribollet, B .

SYNTHETIC METALS, 1999, 102 (1-3) :1381-1382

[4] Polyaniline layer for Iron Protection in sulfate medium [J].

Bernard, MC ;

Hugot-LeGoff, A ;

Joiret, S ;

Dinh, NN ;

Toan, NN .

SYNTHETIC METALS, 1999, 102 (1-3) :1383-1384

[5] Polyaniline layer for iron protection in sulfate medium [J].

Bernard, MC ;

Hugot-Le Goff, A ;

Joiret, S ;

Dinh, NN ;

Toan, NN .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (03) :995-998

[6] Aniline electropolymerization on platinum and mild steel from neutral aqueous media [J].

Camalet, JL ;

Lacroix, JC ;

Nguyen, TD ;

Aeiyach, S ;

Pham, MC ;

Petitjean, J ;

Lacaze, PC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 485 (01) :13-20

[7] Electrodeposition of protective polyaniline films on mild steel [J].

Camalet, JL ;

Lacroix, JC ;

Aeiyach, S ;

ChaneChing, K ;

Lacaze, PC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 416 (1-2) :179-182

[8] Characterization of polyaniline films electrodeposited on mild steel in aqueous p-toluenesulfonic acid solution [J].

Camalet, JL ;

Lacroix, JC ;

Aeiyach, S ;

Lacaze, PC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 445 (1-2) :117-124

[9] Electrosynthesis of adherent polyaniline films on iron and mild steel in aqueous oxalic acid medium [J].

Camalet, JL ;

Lacroix, JC ;

Aeiyach, S ;

Chane-Ching, K ;

Lacaze, PC .

SYNTHETIC METALS, 1998, 93 (02) :133-142

[10]

da Silva JEP, 2000, MACROMOLECULES, V33, P3077