Biodegradable ionic liquids: Selected synthetic applications

被引：31

作者：

Bouquillon, Sandrine

Courant, Thomas

Dean, Darrell

Gathergood, Nicholas ^{[1
]}

Morrissey, Saibh

Pegot, Bruce

Scammells, Peter J.

Singer, Robert D.

机构：

[1] Dublin City Univ, Sch Chem Sci, Natl Inst Cellular Biotechnol, Dublin 9, Ireland

[2] Univ Reims, URF Sci, UMR 6519, F-51687 Reims 2, France

[3] St Marys Univ, Dept Chem, Halifax, NS B3H 3C3, Canada

[4] Monash Univ, Victorian Coll Pharm, Dept Med Chem, Parkville, Vic 3052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2007年 / 60卷 / 11期

基金：

加拿大自然科学与工程研究理事会; 澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH07257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Methyl-1-(propyloxycarbonylmethyl) imidazolium octylsulfate 1a and 3-methyl-1-( pentyloxycarbonylmethyl) imidazolium octylsulfate 2a are ionic liquids that have previously been shown to be readily biodegradable in the CO2 headspace test (ISO 14593). In the present study, these ionic liquids were evaluated as reaction media for Diels-Alder and hydrogenation reactions. The comparison of the performance of these two designer solvents in these reactions with those conducted in other, non-biodegradable ionic liquids has demonstrated that they are comparable and viable solvents.

引用

页码：843 / 847

页数：5

共 25 条

[1] Designing small molecules for biodegradability
Boethling, R. S.
Sommer, Elizabeth
DiFiore, David
[J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2207 - 2227
[2] Heck arylation of allylic alcohols in molten salts
Bouquillon, S
Ganchegui, B
Estrine, B
Hénin, F
Muzart, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 634 (02) : 153 - 156
[3] Pd(II)-dissolved in ionic liquids: A recyclable catalytic system for the selective biphasic hydrogenation of dienes to monoenes
Dupont, J
Suarez, PAZ
Umpierre, AP
de Souza, RF
[J]. JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2000, 11 (03) : 293 - 297
[4] Ionic liquid (molten salt) phase organometallic catalysis
Dupont, J
de Souza, RF
Suarez, PAZ
[J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3667 - 3691
[5] Diels-Alder reactions in ionic liquids - A safe recyclable alternative to lithium perchlorate-diethyl ether mixtures
Earle, MJ
McCormac, PB
Seddon, KR
[J]. GREEN CHEMISTRY, 1999, 1 (01) : 23 - 25
[6] Diels-Alder reactions in room-temperature ionic liquids
Fischer, T
Sethi, A
Welton, T
Woolf, J
[J]. TETRAHEDRON LETTERS, 1999, 40 (04) : 793 - 796
[7] Palladium-catalyzed isomerization of (homo-)allylic alcohols in molten tetrabutylammonium bromide, a recyclable system
Ganchegui, B
Bouquillon, S
Hénin, F
Muzart, J
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (01) : 65 - 69
[8] Palladium-catalyzed dehydrogenation of benzylic alcohols in molten ammonium salts, a recyclable system
Ganchegui, B
Bouquillon, S
Hénin, F
Muzart, J
[J]. TETRAHEDRON LETTERS, 2002, 43 (37) : 6641 - 6644
[9] Biodegradable ionic liquids - Part II. Effect of the anion and toxicology
Garcia, MT
Gathergood, N
Scammells, PJ
[J]. GREEN CHEMISTRY, 2005, 7 (01) : 9 - 14
[10] Design and preparation of room-temperature ionic liquids containing biodegradable side chains
Gathergood, N
Scammells, PJ
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2002, 55 (09) : 557 - 560

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