Asymmetric total synthesis of natural diheteropeptin

被引：4

作者：

Durand, P ^{[1
]}

Peralba, P ^{[1
]}

Derain, V ^{[1
]}

Komesli, S ^{[1
]}

Renaut, P ^{[1
]}

机构：

[1] Lab Fournier SA, F-21121 Daix, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 11期

关键词：

asymmetric dihydroxylation; amino acid synthesis; diheteropeptin; cyclic peptide;

D O I：

10.1016/S0040-4039(01)00139-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A total asymmetric synthesis of diheteropeptin and a stereomer from the known (E)-1-iodo-6-octene, using the Schollkopf method for amino acid synthesis and Sharpless asymmetric dihydroxylation as key steps, is described. The asymmetric synthesis of a new unsaturated amino acid is also described. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：2121 / 2124

页数：4

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