A new straightforward and mild preparation of nickel(0) nanoparticles

被引:38
作者
Alonso, F
Calvino, JJ
Osante, I
Yus, M
机构
[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain
[2] Univ Alicante, ISO, E-03080 Alicante, Spain
[3] Fac Ciencias, Dept Ciencia Mat & Ingn Met & Quim Inorgan, Cadiz 11510, Spain
关键词
D O I
10.1246/cl.2005.1262
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Very fine nickel nanoparticles with diameters of 2.5 +/- 1.5 nm have been prepared by reduction of anhydrous nickel(II) chloride with lithium powder and a catalytic amount of 4,4'di-tert-butylbiphenyl (DTBB) in THF at room temperature.
引用
收藏
页码:1262 / 1263
页数:2
相关论文
共 27 条
[1]   The NiCl2-Li-arene(cat.) combination: A versatile reducing mixture [J].
Alonso, F ;
Yus, M .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (05) :284-293
[2]   The NiCl2-Li-arene (cat.) combination as reducing system, part 9:: Catalytic hydrogenation of organic compounds using the NiCl2-Li-(Naphthalene or polymer-supported naphthalene) (cat.) combination [J].
Alonso, F ;
Candela, P ;
Gómez, C ;
Yus, M .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :275-279
[3]  
Alonso F, 2001, ADV SYNTH CATAL, V343, P188, DOI 10.1002/1615-4169(20010226)343:2<188::AID-ADSC188>3.0.CO
[4]  
2-8
[5]  
ALONSO F, UNPUB
[6]  
BONNEMANN H, 2004, STREM CHEM, V21, P2
[7]  
Bradley J. S., 2004, NANOPARTICLES THEORY, P186
[8]   Synthesis of nickel nanoparticles in water-in-oil microemulsions [J].
Chen, DH ;
Wu, SH .
CHEMISTRY OF MATERIALS, 2000, 12 (05) :1354-1360
[9]   ULTRAVIOLET VISIBLE ABSORPTION-SPECTRA OF THE COLLOIDAL METALLIC ELEMENTS [J].
CREIGHTON, JA ;
EADON, DG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (24) :3881-3891
[10]   Dendrimer-encapsulated metal nanoparticles: Synthesis, characterization, and applications to catalysis [J].
Crooks, RM ;
Zhao, MQ ;
Sun, L ;
Chechik, V ;
Yeung, LK .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :181-190