Structural elucidation of sumanene and generation of its benzylic anions

被引：251

作者：

Sakurai, H ^{[1
]}

Daiko, T ^{[1
]}

Sakane, H ^{[1
]}

Amaya, T ^{[1
]}

Hirao, T ^{[1
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 33期

关键词：

D O I：

10.1021/ja0518169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of sumanene in a solid state was elucidated. The silyl-substituted sumanene was stereoselectively synthesized through generation of the benzylic anions of sumanene. Copyright © 2005 American Chemical Society.

引用

页码：11580 / 11581

页数：2

共 24 条

[1] BOND ALTERNATION IN TRIANNELATED BENZENES - DISSECTION OF CYCLIC PI FROM MILLS NIXON EFFECTS [J].

BALDRIDGE, KK ;

SIEGEL, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9583-9587

[2] DIBENZO[GHI,MNO]FLUORANTHENE [J].

BARTH, WE ;

LAWTON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (02) :380-&

[3] SYNTHESIS AND DYNAMICS OF THE CORANNULENE NUCLEUS [J].

BORCHARDT, A ;

FUCHICELLO, A ;

KILWAY, KV ;

BALDRIDGE, KK ;

SIEGEL, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (05) :1921-1923

[4] Practical synthesis of an open geodesic polyarene with a fullerene-type 6:6-double bond at the center:: Diindeno[1,2,3,4-defg;1′,2′,3′,4′-mnop]chrysene [J].

Bronstein, HE ;

Choi, N ;

Scott, LT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (30) :8870-8875

[5] THERMAL MOTION ANALYSIS IN TRIPHENYLENE - A LATTICE-DYNAMICAL APPROACH [J].

FILIPPINI, G .

JOURNAL OF MOLECULAR STRUCTURE, 1985, 130 (1-2) :117-124

[6] Crystallographic characterization of the molecular structure and solid state packing of the fullerene-shaped hydrocarbon C36H12 [J].

Forkey, DM ;

Attar, S ;

Noll, BC ;

Koerner, R ;

Olmstead, MM ;

Balch, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (24) :5766-5767

[7] MEASURE OF NONPLANARITY IN CONJUGATED ORGANIC-MOLECULES - WHICH STRUCTURALLY CHARACTERIZED MOLECULE DISPLAYS THE HIGHEST DEGREE OF PYRAMIDALIZATION [J].

HADDON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3385-3389

[8] REHYBRIDIZATION AND PI-ORBITAL OVERLAP IN NONPLANAR CONJUGATED ORGANIC-MOLECULES - PI-ORBITAL AXIS VECTOR (POAV) ANALYSIS AND 3-DIMENSIONAL HUCKEL MOLECULAR-ORBITAL (3D-HMO) THEORY [J].

HADDON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) :1676-1685

[9] CRYSTAL AND MOLECULAR-STRUCTURE OF CORANNULENE, C-20H-10 [J].

HANSON, JC ;

NORDMAN, CE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (APR15) :1147-1153

[10] BOND LENGTHS IN FREE MOLECULES OF BUCKMINSTERFULLERENE, C60, FROM GAS-PHASE ELECTRON-DIFFRACTION [J].

HEDBERG, K ;

HEDBERG, L ;

BETHUNE, DS ;

BROWN, CA ;

DORN, HC ;

JOHNSON, RD ;

DEVRIES, M .

SCIENCE, 1991, 254 (5030) :410-412

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