Effects of 2-hydroxyethyl methacrylate on polymer network and interaction in hydrophilic molecularly imprinted polymers

被引:19
作者
Kugimiya, A [1 ]
Takeuchi, T [1 ]
机构
[1] Hiroshima City Univ, Fac Informat Sci, Lab Synthet Biochem, Asaminami Ku, Hiroshima 7313194, Japan
关键词
molecular imprinting; 2-hydroxyethyl methacrylate; hydrophilic property; molecular recognition;
D O I
10.2116/analsci.15.29
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The effects of preparing molecularly imprinted polymers with 2-hydroxyethyl methacrylate (HEMA) were investigated in detail. Polymers prepared with the addition of HEMA showed better separation than polymers prepared without adding HEMA. Since HEMA effects the hydrophilic properties of polymers and/or the crosslinked polymer network, the imprinted polymers prepared with HEMA should allow good separation of the target molecule.
引用
收藏
页码:29 / 33
页数:5
相关论文
共 18 条
  • [1] Molecularly imprinted polymers for bioanalysis: Chromatography, binding assays and biomimetic sensors
    Ansell, RJ
    Kriz, D
    Mosbach, K
    [J]. CURRENT OPINION IN BIOTECHNOLOGY, 1996, 7 (01) : 89 - 94
  • [2] DESIGNED CATALYSTS - A SYNTHETIC NETWORK POLYMER THAT CATALYZES THE DEHYDROFLUORINATION OF 4-FLUORO-4-(P-NITROPHENYL)BUTAN-2-ONE
    BEACH, JV
    SHEA, KJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (01) : 379 - 380
  • [3] Kugimiya A, 1996, ANAL LETT, V29, P1099
  • [4] Synthesis of castasterone selective polymers prepared by molecular imprinting
    Kugimiya, A
    Matsui, J
    Abe, H
    Aburatani, M
    Takeuchi, T
    [J]. ANALYTICA CHIMICA ACTA, 1998, 365 (1-3) : 75 - 79
  • [5] KUGIMIYA A, UNPUB
  • [6] Solid-phase extraction of a triazine herbicide using a molecularly imprinted synthetic receptor
    Matsui, J
    Okada, M
    Tsuruoka, M
    Takeuchi, T
    [J]. ANALYTICAL COMMUNICATIONS, 1997, 34 (03): : 85 - 87
  • [7] Molecular recognition in cinchona alkaloid molecular imprinted polymer rods
    Matsui, J
    Nicholls, IA
    Takeuchi, T
    [J]. ANALYTICA CHIMICA ACTA, 1998, 365 (1-3) : 89 - 93
  • [8] SHEA KJ, 1994, TRENDS POLYM SCI, V2, P166
  • [9] Sreenivasan K, 1998, J APPL POLYM SCI, V68, P1863, DOI 10.1002/(SICI)1097-4628(19980613)68:11<1863::AID-APP18>3.0.CO
  • [10] 2-V