Solvent-free Claisen and Cannizzaro reactions

被引：55

作者：

Yoshizawa, K ^{[1
]}

Toyota, S ^{[1
]}

Toda, F ^{[1
]}

机构：

[1] Okayama Univ Sci, Dept Chem, Okayama 7000005, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 45期

关键词：

solvent-free reaction; Claisen reaction; Cannizzaro reaction; green chemistry;

D O I：

10.1016/S0040-4039(01)01562-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Claisen and Cannizzaro reactions were found to proceed efficiently under solvent-free conditions. The solvent-free Claisen reactions were especially effective for the ester substituted with sterically bulky groups, which does not react in solution. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：7983 / 7985

页数：3

共 10 条

[1]

CUMMING WM, 1950, SYST ORG CHEM, P190

[2] The acetoacetic ester condensation VII The condensation of various alkyl acetates [J].