The metabolites of Trichoderma longibrachiatum .2. The structures of trichodermolide and sorbiquinol

被引:41
作者
Andrade, R [1 ]
Ayer, WA [1 ]
Trifonov, LS [1 ]
机构
[1] UNIV ALBERTA,DEPT CHEM,EDMONTON,AB T6G 2G2,CANADA
来源
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1996年 / 74卷 / 03期
关键词
Trichoderma longibrachiatum; leaf spot disease; coffee; fungal metabolites;
D O I
10.1139/v96-042
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trichoderma longibrachiatum Rifai aggr. is a fungus reported to be antagonistic to the fungus Mycena citricolor, the causative agent of the American leaf spot disease of coffee. We have investigated the metabolites produced when T. longibrachiatum is grown in liquid culture and have isolated several new compounds. The structures of trichodermolide (2) and sorbiquinol (3) were determined by a combination of spectroscopic techniques, including H-1 and C-13 NMR, IR, UV, CD, ORD and mass spectrometry, and by preparation of derivatives.
引用
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页码:371 / 379
页数:9
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