Synthesis of MnO/C composites through a solid state reaction and their transformation into MnO2 nanorods

被引：29

作者：

Hao, Qin ^{[1
]}

Xu, Liqiang ^{[1
]}

Li, Guangda ^{[1
]}

Ju, Zhicheng ^{[1
]}

Sun, Changhui ^{[1
]}

Ma, Houyi ^{[1
]}

Qian, Yitai ^{[1
,2
]}

机构：

[1] Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Shandong, Peoples R China

[2] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2011年 / 509卷 / 21期

关键词：

Composite materials; Oxide materials; Solid state reactions; LITHIUM-ION BATTERIES; FACILE SYNTHESIS; MANGANESE OXIDE; ELECTROCHEMICAL CHARACTERIZATION; MAGNETIC-PROPERTIES; NANOCOMPOSITES; ELECTRODES; NANOWIRES; BEHAVIOR;

D O I：

10.1016/j.jallcom.2011.03.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

MnO nanospheres encapsulated in carbon (MnO/C) composites were synthesized through a one-step solid state reaction between potassium permanganate and salicylic acid at 700 degrees C, which could be transformed into MnO2 nanorods after being annealed in ambient atmosphere. Their formation mechanisms and electrochemical performances as anodes in Li-ion batteries (LIBs) were investigated. The first discharge capacity of MnO/C composites was 585.9 mAh g(-1), while that of MnO2 was 1269 mAh g(-1), indicating their potential applications in LIBs. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：6217 / 6221

页数：5

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