Metal sorbents for high temperature mercury capture from fuel gas

被引：105

作者：

Poulston, Stephen ^{[1
]}

Granite, Evan J.

Pennline, Henry W.

Myers, Christina R.

Stanko, Dennis P.

Hamilton, Hugh

Rowsell, Liz

Smith, Andrew W. J.

Ilkenhans, Thomas

Chu, Wilson

机构：

[1] Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England

[2] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA

[3] Stationary Source Emiss Control, Malvern, PA 19382 USA

来源：

FUEL | 2007年 / 86卷 / 14期

关键词：

mercury; coal; gasification;

D O I：

10.1016/j.fuel.2007.05.015

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

have determined the Hg removal capacities of Pt and Pd supported on alumina at a range of different metal loadings from 2 to 9 wt%,, using Hg vapour in a simulated fuel gas feed. In the temperature range studied (204-388 degrees C) Pd proved far superior to Pt for Hg removal. The Hg removal capacity for both Pt and Pd increased with metal loading, though decreased with sorbent temperature. A shift in the 20 position of the Pd XRD diffraction peak from 82.1 to 79.5 after Hg adsorption at 204 degrees C was consistent with the formation of a solid solution of fig in Pd. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2201 / 2203

页数：3

共 11 条

[1]

CUMINSKI C, 1990, B ALLOY PHASE DIAG, V11, P26

[2] Sorbents for mercury capture from fuel gas with application to gasification systems [J].

Granite, Evan J. ;

Myers, Christina R. ;

King, William P. ;

Stanko, Dennis C. ;

Pennline, Henry W. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (13) :4844-4848

[3]

Guminski C., 1990, B ALLOY PHASE DIAGRA, V11, P22

[4] Development of cost-effective noncarbon sorbents for Hg0 removal from coal-fired power plants [J].

Lee, JY ;

Ju, YH ;

Keener, TC ;

Varma, RS .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (08) :2714-2720

[5] Volatilization of mercury, arsenic and selenium during underground coal gasification [J].

Liu, Shuqin ;

Wang, Yongtao ;

Yu, Li ;

Oakey, John .

FUEL, 2006, 85 (10-11) :1550-1558

[6] Retention of mercury in activated carbons in coal combustion and gasification flue gases [J].

Lopez-Antón, MA ;

Tascón, JMD ;

Martínez-Tarazona, MR .

FUEL PROCESSING TECHNOLOGY, 2002, 77 (77-78) :353-358

[7] Study of mercury speciation from simulated coal gasification [J].

Lu, DY ;

Granatstein, DL ;

Rose, DJ .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (17) :5400-5404

[8] Development of novel sorbents for mercury control at elevated temperatures in coal-derived syngas: results of initial screening of candidate materials [J].

Portzer, JW ;

Albritton, JR ;

Allen, CC ;

Gupta, RP .

FUEL PROCESSING TECHNOLOGY, 2004, 85 (6-7) :621-630

[9] Control of gasifier mercury emissions in a hot gas filter:: the effect of temperature [J].

Reed, GP ;

Ergüdenler, A ;

Grace, JR ;

Watkinson, AP ;

Herod, AA ;

Dugwell, D ;

Kandiyoti, R .

FUEL, 2001, 80 (05) :623-634

[10] SOLID SOLUTION OF MERCURY IN PALLADIUM [J].

TERADA, K ;

CAGLE, FW .

ACTA CRYSTALLOGRAPHICA, 1961, 14 (12) :1299-&

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