Low-temperature sintering and piezoelectric properties of CuO-added 0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics

被引:89
作者
Park, Hwi-Yeol
Ahn, Cheol-Woo
Cho, Kyung-Hoon
Nahm, Sahn [1 ]
Lee, Hyeung-Gyu
Kang, Hyung-Won
Kim, Duk-Hee
Park, Kyeong-Soon
机构
[1] Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
[2] Korea Elect Technol Inst, Gyeonggi Do 463816, South Korea
[3] Innochips Tecnol, Kyonggi Do 429010, South Korea
[4] Sejong Univ, Dept Adv Mat Engn, Seoul 143747, South Korea
关键词
Grain growth - Grain size and shape - Piezoelectricity - Sintering - Solid state reactions;
D O I
10.1111/j.1551-2916.2007.02070.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The sintering temperature of 0.95(Na0.5K0.5)NbO3-0.05BaTiO(3) (NKN-BT) ceramics needs to be decreased below 1000 degrees C to prevent Na2O evaporation, which can cause difficulties in poling and may eventually degrade their piezoelectric properties. NKN-BT ceramics containing CuO were well sintered at 950 degrees C with grain growth. Poling was easy for all specimens. Densification and grain growth were explained by the formation of a liquid phase. The addition of CuO improved the piezoelectric properties by increasing the grain size and density. High piezoelectric properties of d(33) = 230 pC/N, k(p) = 37%, and epsilon(T)(3)/epsilon(0)=1150 were obtained from the specimen containing 1.0 mol% of CuO synthesized by the conventional solid-state method.
引用
收藏
页码:4066 / 4069
页数:4
相关论文
共 18 条
[1]   Effect of ZnO and CuO on the sintering temperature and piezoelectric properties of a hard piezoelectric ceramic [J].
Ahn, CW ;
Song, HC ;
Nahm, S ;
Priya, S .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (03) :921-925
[2]   Effect of the liquid-forming additive content on the kinetics of abnormal grain growth in alumina [J].
Ahn, JH ;
Lee, JH ;
Hong, SH ;
Hwang, NM ;
Kim, DY .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2003, 86 (08) :1421-1423
[3]   Dielectric and piezoelectric properties of lead-free (Na0.5K0.5)NbO3-SrTiO3 ceramics [J].
Guo, YP ;
Kakimoto, K ;
Ohsato, H .
SOLID STATE COMMUNICATIONS, 2004, 129 (05) :279-284
[4]   Structure and electrical properties of lead-free (Na0.5K0.5)Nbo3-BaTiO3 ceramics [J].
Guo, YP ;
Kakimoto, K ;
Ohsato, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2004, 43 (9B) :6662-6666
[5]   Phase transitional behavior and piezoelectric properties of (Na0.5K0.5)NbO3-LiNbO3 ceramics [J].
Guo, YP ;
Kakimoto, K ;
Ohsato, H .
APPLIED PHYSICS LETTERS, 2004, 85 (18) :4121-4123
[6]   Piezoelectric properties of Li- and Ta-modified (K0.5Na0.5)NbO3 ceramics -: art. no. 182905 [J].
Hollenstein, E ;
Davis, M ;
Damjanovic, D ;
Setter, N .
APPLIED PHYSICS LETTERS, 2005, 87 (18) :1-3
[7]   Ferroelectric and piezoelectric properties of kNbO3 ceramics containing small amounts of LaFeO3 [J].
Kakimoto, K ;
Masuda, I ;
Ohsato, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2003, 42 (9B) :6102-6105
[8]   Effect of B2O3 and CuO additives on the sintering temperature and microwave dielectric properties of Ba(Zn1/3Nb2/3)O3 ceramics [J].
Kim, Min-Han ;
Jeong, Young-Hun ;
Nahm, Sahn ;
Kim, Hyo-Tae ;
Lee, Hwack-Joo .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (10-11) :2139-2142
[9]   Effect of B2O3 and CuO additives on the sintering temperature and microwave dielectric properties of Ba(Mg1/3Nb2/3)O3 ceramics [J].
Lim, Jong-Bong ;
Kim, Dong-Hyun ;
Nahm, Sahn ;
Paik, Jong-Hoo ;
Lee, Hwack-Joo .
MATERIALS RESEARCH BULLETIN, 2006, 41 (06) :1199-1205
[10]   Processing and piezoelectric properties of lead-free (K,Na) (Nb,Ta) O3 ceramics [J].
Matsubara, M ;
Yamaguchi, T ;
Sakamoto, W ;
Kikuta, K ;
Yogo, T ;
Hirano, S .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (05) :1190-1196