A novel convenient method to synthesize unsymmetrical 1,1′-disubstituted ferrocenes consisting of various phosphino, thiolato and pyridyl substituents

被引：17

作者：

Dong, TY ^{[1
]}

Chang, CK ^{[1
]}

机构：

[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1998年 / 45卷 / 05期

关键词：

ferrocene; unsymmetrical 1,1 '-disubstituted ferrocenes;

D O I：

10.1002/jccs.199800087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel convenient method for preparing unsymmetrical 1,1'-disubstituted ferrocenyl phosphine ligands by using the readily accessible 1,12'-diblomoferrocene as a precursor is described. The method is of interest for modifying the chelating ferrocenyl phosphine ligands in view of the growing influence of homogeneous catalysis in organic synthesis, manipulation of materials and production of high optical yield.

引用

页码：577 / 579

页数：3

共 13 条

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