Spectroelectrochemical study of N-ethyl-carbazole in the presence of acrylamide

被引：11

作者：

Yavuz, Ö ^{[1
]}

Sezer, E ^{[1
]}

Saraç, AS ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, Fac Sci & Letters, TR-80626 Istanbul, Turkey

来源：

POLYMER INTERNATIONAL | 2001年 / 50卷 / 03期

关键词：

N-ethylcarbazole; acrylamide; in situ spectroelectrochemical measurements;

D O I：

10.1002/pi.616

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymerization of N-ethylcarbazole (NECz) in the presence of acrylamide (AAm) has been investigated by in situ and ex situ UV-visible spectrophotometric measurements to obtain information about the reaction pathway, because NECz gives soluble oligomeric species allowing such measurements. A tentative mechanism is proposed in the light of these results. The redox properties of the new polymers have been studied for possible sensor application. (C) 2001 Society of Chemical Industry.

引用

页码：271 / 276

页数：6

共 18 条

[1] ANODIC OXIDATION PATHWAYS OF CARBAZOLES .1. CARBAZOLE AND N-SUBSTITUTED DERIVATIVES [J].

AMBROSE, JF ;

NELSON, RF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1968, 115 (11) :1159-&

[2] ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES OF CATION RADICALS .3. REACTION PATHWAYS OF CARBAZOLIUM RADICAL IONS [J].

AMBROSE, JF ;

CARPENTER, LL ;

NELSON, RF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (07) :876-894

[3] ELECTROCHEMICAL SYNTHESIS OF ELECTRICALLY CONDUCTING POLYMERS FROM AROMATIC-COMPOUNDS [J].

BARGON, J ;

MOHMAND, S ;

WALTMAN, RJ .

IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 1983, 27 (04) :330-341

[4]

BERG WF, 1972, CURRENT PROBLEMS ELE

[5]

BISWAS M, 1982, POLYMER, V23, P1713, DOI 10.1016/0032-3861(82)90112-4

[6]

BLOCK H, 1979, ADV POLYM SCI, V33, P93

[7] SYNTHESIS AND PROPERTIES OF FILM ELECTRODES FROM N-SUBSTITUTED CARBAZOLES IN ACID-MEDIUM [J].

CATTARIN, S ;

MENGOLI, G ;

MUSIANI, MM ;

SCHRECK, B .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 246 (01) :87-100

[8] POLAROMICROTRIBOMETRIC (PMT) AND IR, ESCA, ELECTRON-PARAMAGNETIC-RES SPECTROSCOPIC STUDY OF COLORED RADICAL FILMS FORMED BY THE ELECTROCHEMICAL OXIDATION OF CARBAZOLES .1. CARBAZOLE AND N-ETHYL, N-PHENYL AND N-CARBAZYL DERIVATIVES [J].

DESBENEMONVERNAY, A ;

LACAZE, PC ;

DUBOIS, JE .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1981, 129 (1-2) :229-241

[9]

KUFMAN FB, 1980, APPL PHYS LETT, V36, P422

[10]

MONVERNAY AD, 1986, J ELECTROANAL CHEM, V199, P449

← 1 2 →