The first synthesis of a conjugated hybrid of C60-fullerene and a single-wall carbon nanotube

被引：46

作者：

Delgado, Juan Luis

de la Cruz, Pilar

Urbina, Antonio

Navarrete, Juan T. Lopez

Casado, Juan

Langa, Fernando ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Ciencias Med Ambience, Toledo 45071, Spain

[2] Univ Politec Cartagena, Murcia 30202, Spain

[3] Univ Malaga, Dept Quim Fis, E-29071 Malaga, Spain

来源：

CARBON | 2007年 / 45卷 / 11期

关键词：

D O I：

10.1016/j.carbon.2007.06.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first synthesis of a conjugated hybrid Of C-60-fullerene and a single-wall carbon nanotube (SWCNT) is reported. The new nano-hybrid material has been prepared by amidation of acid functionalized SWCNTs by an amine functionalized-fullerene derivative. The formation of this new nanomaterial was demonstrated by high resolution TEM, attenuated total reflectance/FTIR and Raman spectroscopy. Acid hydrolysis of the new material produced carboxylic-SWCNTs and the recovery of the aminofullerene derivative as complementary evidence of their covalent link. This new SWCNT-fullerene material may be of interest in optoelectronic applications. (c) 2007 Elsevier Ltd. All rights reserved.

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页码：2250 / 2252

页数：3

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