Carbene transposition involving double dehydrogenation of an sp3 carbon

被引：22

作者：

Coalter, JN

Huffman, JC

Caulton, KG ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 13期

关键词：

D O I：

10.1039/b102422c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two benzylic hydrogens of 2,6-Me2C6H3O- coordinated to RuCl(PCy3)(2)(CHPh)(+) are transferred to the benzylidene ligand, liberating toluene to form a new carbene which is covalently linked to the aryloxide ligand.

引用

页码：1158 / 1159

页数：2

共 10 条

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[10] 2-8

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