Cartilagineol, the fourth lineage of Laurencia-derived polyhalogenated chamigrene

被引：15

作者：

Francisco, MEY ^{[1
]}

Turnbull, MM ^{[1
]}

Erickson, KL ^{[1
]}

机构：

[1] Clark Univ, Carlson Sch Chem, Worcester, MA 01610 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 30期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(98)01011-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A revised regiochemistry and the absolute configuration are established for cartilagineol (formerly allo-isoobtusol). This revised structure renders cartilagineol the first example of die fourth stereochemical type of Laurencia-derived polyhalogenated chamigrene in support of current biogenetic theory. Earlier misassigned NMR data for ma'ilione is corrected. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5289 / 5292

页数：4

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