Development of a New s-Tetrazine-Based Copolymer for Efficient Solar Cells

被引：144

作者：

Li, Zhao ^{[1
]}

Ding, Jianfu ^{[1
]}

Song, Naiheng ^{[1
]}

Lu, Jianping ^{[2
]}

Tao, Ye ^{[2
]}

机构：

[1] NRCC, ICPET, Ottawa, ON K1A 0R6, Canada

[2] NRCC, IMS, Ottawa, ON K1A 0R6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 38期

关键词：

SUBSTITUTED TETRAZINES; CONJUGATED POLYMERS; PERFORMANCE; CONVERSION; SEPARATION;

D O I：

10.1021/ja106052e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new s-tetrazine-based low-bandgap semiconducting polymer, PCPDTTTz, was designed and synthesized. This is the first solution-processable conjugated polymer with tetrazine in the main chain. This polymer shows good thermal stability and broad absorption covering 450-700 nm. The HOMO and LUMO energy levels were estimated to be -5.34 and -3.48 eV, with an electrochemical bandgap of 1.86 eV. Simple polymer solar cells based on PCPDTTTz and PC71BM exhibit a calibrated power conversion efficiency of 5.4%.

引用

页码：13160 / 13161

页数：2

共 38 条

[1]

Asawapirom U, 2001, MACROMOL RAPID COMM, V22, P746, DOI 10.1002/1521-3927(20010701)22:10<746::AID-MARC746>3.0.CO

[2]

2-H

[3] Synthesis of new substituted tetrazines:: electrochemical and spectroscopic properties [J].