The tris(4-tert-butylphenyl)methyl group:: A bulky substituent for effective regioselective difunctionalisation of cyclomaltohexaose

被引：42

作者：

Armspach, D ^{[1
]}

Matt, D ^{[1
]}

机构：

[1] Univ Strasbourg 1, UMR 7513 CNRS, Grp Chim Inorgan Mol, F-67008 Strasbourg, France

来源：

CARBOHYDRATE RESEARCH | 1998年 / 310卷 / 1-2期

关键词：

alpha-cyclodextrin; cyclomaltohexaase functionalisation; tris(4-tert-butylphenyl)methyl;

D O I：

10.1016/S0008-6215(98)00139-6

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

Methodology based on the use of the "supertrityl" group (= -C(p-Bu-t-C6H4)(3)) allows convenient difunctionalisation of cyclomaltohexaose. The AD regioisomer was obtained in an overall yield of 30%. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：129 / 133

页数：5

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