Mutual diffusion measurements in a ternary system:: Ionic surfactant nonionic surfactant water at 25 °C

被引:40
作者
Castaldi, M [1 ]
Costantino, L [1 ]
Ortona, O [1 ]
Paduano, L [1 ]
Vitagliano, V [1 ]
机构
[1] Univ Naples, Dipartimento Chim, I-80134 Naples, Italy
关键词
D O I
10.1021/la980457a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The four diffusion coefficients describing the isothermal transport process in ternary systems have been measured in aqueous solutions of mixed surfactants. Measurements have been made on the system pentaethyleneglycol 1-hexyl ether-sodium 1-hexanesulfonate-water at various mean compositions. The analysis of diffusion data allows a reasonable interpretation of the behavior of mixed surfactant solutions, showing the evidence of the presence of mixed micelles.
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页码:5994 / 5998
页数:5
相关论文
共 28 条
[1]  
ALBRIGHT JG, 1989, J PHYS CHEM-US, V93, P2163
[2]   Thermodynamic and dynamic properties of micellar aggregates of nonionic surfactants with short hydrophobic tails [J].
Ambrosone, L ;
Costantino, L ;
DErrico, G ;
Vitagliano, V .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 190 (02) :286-293
[3]  
CICCARELLI D, UNPUB LANGMUIR
[4]   MICELLIZATION OF MIXED NONIONIC SURFACE-ACTIVE AGENTS [J].
CLINT, JH .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (06) :1327-1334
[5]   Mutual diffusion coefficients and resistance coefficients for aqueous solutions of sodium alkanoate surfactants [J].
Deng, ZP ;
Lu, H ;
Leaist, DG .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (02) :214-217
[6]   THERMODYNAMIC PROPERTIES OF ALKYLDIMETHYLAMINE OXIDES IN WATER - APPLICATION OF A MASS-ACTION MODEL FOR MICELLIZATION [J].
DESNOYERS, JE ;
CARON, G ;
DELISI, R ;
ROBERTS, D ;
ROUX, A ;
PERRON, G .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (08) :1397-1406
[7]   SURFACTANT DIFFUSION - NEW RESULTS AND INTERPRETATIONS [J].
EVANS, DF ;
MUKHERJEE, S ;
MITCHELL, DJ ;
NINHAM, BW .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 93 (01) :184-204
[8]   A NEW PROCEDURE FOR CALCULATING THE 4 DIFFUSION COEFFICIENTS OF 3-COMPONENT SYSTEMS FROM GOUY DIFFUSIOMETER DATA [J].
FUJITA, H ;
GOSTING, LJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (09) :1256-1263
[9]   AN EXACT SOLUTION OF THE EQUATIONS FOR FREE DIFFUSION IN 3-COMPONENT SYSTEMS WITH INTERACTING FLOWS, AND ITS USE IN EVALUATION OF THE DIFFUSION COEFFICIENTS [J].
FUJITA, H ;
GOSTING, LJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (06) :1099-1106
[10]   NONIDEAL MULTICOMPONENT MIXED MICELLE MODEL [J].
HOLLAND, PM ;
RUBINGH, DN .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (11) :1984-1990