Formation of YSZ-SDC solid solution in a nanocrystalline heterophase system and its effect on the electrical conductivity

被引:44
作者
Price, M
Dong, JH [1 ]
Gu, XH
Speakman, SA
Payzant, EA
Nenoff, TM
机构
[1] New Mexico Inst Min & Technol, Dept Chem & Petr Engn, New Mexico Petr Recovery Res Ctr, Socorro, NM 87801 USA
[2] Oak Ridge Natl Lab, Div Met & Ceram, Oak Ridge, TN 37831 USA
[3] Sandia Natl Labs, Albuquerque, NM 87185 USA
关键词
D O I
10.1111/j.1551-2916.2005.00389.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The stability of an yttria-stabilized zirconia and samaria-doped ceria (YSZ-SDC) nanocrystalline heterophase system was studied with in situ high-temperature X-ray diffraction during a simulated sintering program. Formation of YSZ-SDC solid solution in the nanocrystalline system was found to start at a low temperature between 900 degrees and 950 degrees C. The analysis of lattice parameters as a function of temperature suggested that YSZ and SDC species diffused mutually during the formation of solid solution. The electrical conductivity of the YSZ-SDC solid solution was significantly lower than that of the YSZ and SDC.
引用
收藏
页码:1812 / 1818
页数:7
相关论文
共 20 条
[1]  
Ananthapadmanabhan P. V., 1990, Journal of the European Ceramic Society, V6, P111, DOI 10.1016/0955-2219(90)90044-G
[2]  
[Anonymous], [No title captured]
[3]   Characterisation of ceria-zirconia solid solutions after hydrothermal ageing [J].
Bozo, C ;
Gaillard, F ;
Guilhaume, N .
APPLIED CATALYSIS A-GENERAL, 2001, 220 (1-2) :69-77
[4]   Surface energies and heats of oxygen adsorption in ceria/ceria-zirconia solid solutions: Analysis by semiempirical interacting bonds method [J].
Bulgakov, NN ;
Sadykov, VA ;
Lunin, VV ;
Kemnitz, E .
REACTION KINETICS AND CATALYSIS LETTERS, 2002, 76 (01) :111-116
[5]  
Chavan SV, 2004, J AM CERAM SOC, V87, P1977
[6]   Grain growth in nanocrystalline yttrium-stabilized zirconia thin films synthesized by spin coating of polymeric precursors [J].
Dong, JH ;
Hu, MZ ;
Payzant, EA ;
Armstrong, TR ;
Becher, PF .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2002, 2 (02) :161-169
[7]   A low-operating-temperature solid oxide fuel cell in hydrocarbon-air mixtures [J].
Hibino, T ;
Hashimoto, A ;
Inoue, T ;
Tokuno, J ;
Yoshida, S ;
Sano, M .
SCIENCE, 2000, 288 (5473) :2031-2033
[8]   STUDY OF A SOLID OXIDE FUEL-CELL WITH A CERIA-BASED SOLID ELECTROLYTE [J].
INOUE, T ;
SETOGUCHI, T ;
EGUCHI, K ;
ARAI, H .
SOLID STATE IONICS, 1989, 35 (3-4) :285-291
[9]   Preparation of YSZ/YDC and YSZ/GDC composite electrolytes by the tape casting and sol-gel dip-drawing coating method for low-temperature SOFC [J].
Jang, WS ;
Hyun, SH ;
Kim, SG .
JOURNAL OF MATERIALS SCIENCE, 2002, 37 (12) :2535-2541
[10]   Investigation of electrical conductivity as a function of dopant-ion radius in the systems Zr0.75Ce0.08M0.17O1.92 (M=Nd, Sm, Gd, Dy, Ho, Y, Er, Yb, Sc) [J].
Kimpton, J ;
Randle, TH ;
Drennan, J .
SOLID STATE IONICS, 2002, 149 (1-2) :89-98