Influence of aluminum on the thermal decomposition of hexabromocyclododecane

被引：13

作者：

Barontini, F

Cozzani, V

Petarca, L

机构：

[1] Univ Pisa, Dipartimento Chim Chim Ind & Sci Mat, I-56126 Pisa, Italy

[2] CNR, Grp Nazl Difesa Rischi Chim Ind Ecol, I-56126 Pisa, Italy

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2003年 / 70卷 / 02期

关键词：

hexabromocyclododecane; aluminum; thermal degradation; brominated flame retardants; pyrolysis products;

D O I：

10.1016/S0165-2370(02)00182-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The influence of aluminum on the thermal stability of hexabromocyclododecane (HBCD) was investigated. HBCD pyrolysis was carried out using thermogravimetric analyzers and a laboratory scale reactor. The identification of decomposition products was based on FTIR and gas-chromatographic/mass-spectrometric techniques. The results obtained confirmed that the presence of aluminum caused a lower thermal stability of HBCD. However, the presence of aluminum also resulted in a significant increase of the char yield and caused the shift towards an exothermic decomposition process. The analysis of the decomposition products showed that the presence of aluminum triggers polycondensation reactions during HBCD thermal degradation. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：353 / 368

页数：16

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