Nickel(II) complexes bound to an [Fe4S4] cluster via bridging thiolates: Synthesis and crystal structures of model compounds for the active site of nickel CO dehydrogenase

被引：28

作者：

Osterloh, F ^{[1
]}

Saak, W ^{[1
]}

Haase, D ^{[1
]}

Pohl, S ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,D-26111 OLDENBURG,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 06期

关键词：

D O I：

10.1039/cc9960000777

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[NiL][L = (SCH2CH2N)-S--(Et)CH2CH2CH2N(Et)CH2CH2S-] 1 reacts with [Fe4S4I4](2-) to afford [(NiL)(2)Fe4S4I2] 3; in 3 the two fragments of 1 are doubly bridged via mu-sulfur of L to iron atoms of the [Fe4S4] core.

引用

页码：777 / 778

页数：2

共 31 条

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