Determination of reactivity ratios for ethylene/alpha-olefin copolymerization catalysed by the C2H4[Ind]2ZrCl2/methylaluminoxane system

被引：46

作者：

Galland, GB

Quijada, P

Mauler, RS

deMenezes, SC

机构：

[1] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT INGN QUIM,SANTIAGO,CHILE

[2] PETROBRAS SA,CENPES,DIQUIM,RIO JANEIRO,BRAZIL

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 09期

关键词：

D O I：

10.1002/marc.1996.030170901

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The present study reports values of reactivity ratios for ethylene/1-hexene, ethylene/1-octene and ethylene/1-decene copolymerizations promoted by C2H4[Ind]2ZrCl2/MAO. The comonomer reactivities are markedly influenced by the number of carbon atoms of the alpha-olefin. The ethylene/1-decene copolymerization depends on the concentration of alpha-olefin in the feed.

引用

页码：607 / 613

页数：7

共 9 条

[1] BIS-(CYCLOPENTADIENYL)-TITANIUM DICHLORIDE-ALKYLALUMINUM COMPLEXES AS CATALYSTS FOR THE POLYMERIZATION OF ETHYLENE [J].