Use of thermogravimetric analysis Fourier transform infrared spectroscopy in the study of the reaction mechanism of the preparation of Pb(Zr,Ti)O-3 by the sol-gel method

被引：46

作者：

Nouwen, R ^{[1
]}

Mullens, J ^{[1
]}

Franco, D ^{[1
]}

Yperman, J ^{[1
]}

VanPoucke, LC ^{[1
]}

机构：

[1] LIMBURGS UNIV CENTRUM,LAB INORGAN & PHYS CHEM,B-3590 DIEPENBEEK,BELGIUM

来源：

VIBRATIONAL SPECTROSCOPY | 1996年 / 10卷 / 02期

关键词：

infrared spectrometry; thermogravimetry; Pb(Zr; Ti)O-3; sol-gel method;

D O I：

10.1016/0924-2031(95)00033-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The thermal decomposition of a sol-gel precursor of Pb(Zr, Ti)O-3 is studied by thermogravimetric analysis-Fourier transform infrared spectroscopy in argon and in air. It is found that in an inert atmosphere the presence of residual carbon inhibits the formation of the perovskite structure. In air the evolution of volatile compounds such as alcohols, esters, ethers and CO2 at temperatures above 300 degrees C indicate that polymerization is still going on during the thermal decomposition of the precursor.

引用

页码：291 / 299

页数：9

共 11 条

[1] REACTIONS TAKING PLACE DURING THE SOL-GEL PROCESSING OF PLZT [J].

BELTRAM, T ;

KOSEC, M ;

STAVBER, S .

MATERIALS RESEARCH BULLETIN, 1993, 28 (04) :313-320

[2] SOL-GEL-DERIVED PBTIO3 [J].

BLUM, JB ;

GURKOVICH, SR .

JOURNAL OF MATERIALS SCIENCE, 1985, 20 (12) :4479-4483

[3]

BRINKER CJ, 1990, SOL GEL SCI, P43

[4] CHEMICAL ASPECTS OF SOLUTION ROUTES TO PEROVSKITE-PHASE MIXED-METAL OXIDES FROM METAL-ORGANIC PRECURSORS [J].

CHANDLER, CD ;

ROGER, C ;

HAMPDENSMITH, MJ .

CHEMICAL REVIEWS, 1993, 93 (03) :1205-1241

[5] COMPOSITIONAL FLUCTUATION AND PROPERTIES OF PB(ZR,TI)O3 [J].

KAKEGAWA, K ;

MOHRI, J ;

TAKAHASHI, T ;

YAMAMURA, H ;

SHIRASAKI, S .

SOLID STATE COMMUNICATIONS, 1977, 24 (11) :769-772

[6] THE CHEMISTRY OF THE SOL-GEL PROCESS [J].

LIVAGE, J ;

SANCHEZ, C ;

HENRY, M ;

DOEUFF, S .

SOLID STATE IONICS, 1989, 32-3 :633-638

[7] PREPARATION AND PROPERTIES OF PBTIO3 FILMS BY SOL-GEL PROCESSING [J].

MAEDA, M ;

ISHIDA, H ;

SOE, KKK ;

SUZUKI, I .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (9B) :4136-4140

[8] COUPLING BETWEEN FTIR (BRUKER IFS 66) AND TG (DU-PONT TGA 951-2000) [J].

MULLENS, J ;

CARLEER, R ;

REGGERS, G ;

YPERMAN, J ;

VANHEES, J ;

VANPOUKE, LC .

THERMOCHIMICA ACTA, 1992, 212 :219-225

[9] THE DECOMPOSITION OF COPPER OXALATE TO METALLIC COPPER IS WELL SUITED FOR CHECKING THE INERT WORKING-CONDITIONS OF THERMAL-ANALYSIS EQUIPMENT [J].

MULLENS, J ;

VOS, A ;

CARLEER, R ;

YPERMAN, J ;

VANPOUCKE, LC .

THERMOCHIMICA ACTA, 1992, 207 :337-339

[10] SOL-GEL PROCESSING OF PBTIO3 AND PB(ZR(0.52)TI(0.48))O3 FIBERS [J].

SELVARAJ, U ;

PRASADARAO, AV ;

KOMARNENI, S ;

BROOKS, K ;

KURTZ, S .

JOURNAL OF MATERIALS RESEARCH, 1992, 7 (04) :992-996

← 1 2 →