[TmIII(hfac)3(NITPhOPh)]∞:: A new member of a lanthanide-based single chain magnets family

被引：97

作者：

Bernot, K.

Bogani, L.

Sessoli, R.

Gatteschi, D.

机构：

[1] Univ Stud Firenze, Dept Chem & INSTM, I-50019 Sesto Fiorentino, Italy

[2] INSA Rennes, UMR 6226 CNRS, Sci Chimniques Rennes, F-35043 Rennes, France

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 13期

关键词：

nitronyl-nitroxides; single chain magnets; lanthanides; magnetic anisotropy;

D O I：

10.1016/j.ica.2006.12.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polymeric coordination compound of formula [Tm(hfaC)(3)(NITPhOPh)](infinity) (where NITPhOPh is a nitronyl-nitroxide radical) has been synthesized and found to belong to the only reported family of isostructural Single Chain Magnets. Both static and dynamic magnetic measurements have been performed, and a dependence of the out-of-phase signal on the frequency is observed below 3 K. Scaling procedures indicate Ising magnetic anisotropy. Comparison of the extracted parameters with those of the previously reported isostructural compounds confirms a trend along the lanthanide series. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3807 / 3812

页数：6

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