Bifunctional Au@Pt hybrid nanorods

被引:50
作者
Guo, Shaojun
Wang, Liang
Wang, Wing
Fang, Youxing
Wang, Erkang [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanal Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
gold nanorod; catalysis; SERS; hybrid material; platinum nanoparticle;
D O I
10.1016/j.jcis.2007.06.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The controlled synthesis of bifunctional Au@Pt hybrid nanorods has been realized through a simple wet chemical approach. Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and UV-vis-near infrared spectroscopy (UV-vis-NIR) were employed to characterize the obtained hybrid nanorods. TEM results indicate that the thickness of Pt nanoislands on the surfaces of gold nanorods can be easily tunable via controlling the molar ratio of An nanorods to the H2PtCl6. These Au@Pt hybrid nanorods have dual functions, which can be used not only for surface enhanced Raman spectroscopy (SERS), but also to exhibit good catalytic activity for 02 reduction. It is expected that these hybrid nanorods can be used as new functional building blocks to assemble novel three-dimensional (31)) complex multicomponent nanostructures, which are believed to be useful for electrochemical nanodevices. (C) 2007 Elsevier Inc. All rights reserved.
引用
收藏
页码:363 / 368
页数:6
相关论文
共 31 条
[1]   Preparation of AucoreAgshell nanorods and characterization of their surface plasmon resonances [J].
Ah, CS ;
Do Hong, S ;
Jang, DJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (33) :7871-7873
[2]   Surface-enhanced Raman scattering [J].
Campion, A ;
Kambhampati, P .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :241-250
[3]   Optical properties of Pd-Ag and Pt-Ag nanoboxes synthesized via galvanic replacement reactions [J].
Chen, JY ;
Wiley, B ;
McLellan, J ;
Xiong, YJ ;
Li, ZY ;
Xia, YN .
NANO LETTERS, 2005, 5 (10) :2058-2062
[4]   Preparation of colloidal silver-palladium alloys by UV-irradiation in mixtures of acetone and 2-propanol [J].
Esumi, K ;
Wakabayashi, M ;
Torigoe, K .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1996, 109 :55-62
[5]   In situ surface enhanced Raman spectroscopy on electrodes with platinum and palladium nanoparticle ensembles [J].
Gómez, R ;
Pérez, JM ;
Solla-Gullón, J ;
Montiel, V ;
Aldaz, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (28) :9943-9949
[6]   Synthesis of Au@Pd core-shell nanoparticles with controllable size and their application in surface-enhanced Raman spectroscopy [J].
Hu, JW ;
Zhang, Y ;
Li, JF ;
Liu, Z ;
Ren, B ;
Sun, SG ;
Tian, ZQ ;
Lian, T .
CHEMICAL PHYSICS LETTERS, 2005, 408 (4-6) :354-359
[7]   Synthesis of dumbbell-shaped Au-Ag core-shell nanorods by seed-mediated growth under alkaline conditions [J].
Huang, CC ;
Yang, ZS ;
Chang, HT .
LANGMUIR, 2004, 20 (15) :6089-6092
[8]   Surface-enhanced Raman scattering at Pt nanoaggregates [J].
Kim, NH ;
Kim, K .
CHEMICAL PHYSICS LETTERS, 2004, 393 (4-6) :478-482
[9]   Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nanodots and nanorods [J].
Link, S ;
El-Sayed, MA .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (40) :8410-8426
[10]   Synthesis and optical characterization of Au/Ag core/shell nanorods [J].
Liu, MZ ;
Guyot-Sionnest, P .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (19) :5882-5888