Consequences of Partial Flexibility in 1,3-Benzenedicarboxylate Linkers: Kagome Lattice and NbO Supramolecular Isomers from Complexation of a Bulky 1,3-Benzenedicarboxylate to Cu(II) Paddlewheel Moieties

被引：39

作者：

Zhang, Zhenjie ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Zaworotko, Michael J. ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 05期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; GAS-SORPTION; BUILDING-BLOCKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; DESIGN; ADSORPTION; POLYHEDRA; BDC;

D O I：

10.1021/cg200183x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 5-substituted benzene-1,3-dicarboxylic acid (1,3-BDC), 5-(N-phthalimide)isophthalic acid (5-NPIA), reacts with CuCl2 to afford either a Kagome lattice or NbO nets, depending upon which solvent is used for the reaction.

引用

页码：1441 / 1445

页数：5

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