Comprehensive approach to determining the physical properties of granular activated carbons

被引:24
作者
Chiang, YC
Chiang, PC
Chang, EE
机构
[1] Natl Taiwan Univ, Grad Inst Environm Engn, Taipei 10764, Taiwan
[2] Taipei Med Coll, Dept Analyt Chem, Taipei, Taiwan
关键词
activated carbon; hysteresis loop; composite approach; pore size distribution; factor analysis;
D O I
10.1016/S0045-6535(98)00042-3
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The objectives of this research were to identify the physical characteristics of activated carbons manufactured by peat, bituminous coal and coconut shell as well as examine the correlation among these properties. The helium density and mercury density were measured by using the recommended standard methods; in addition, the adsorption isotherms of nitrogen, argon and mercury were reported by using the automatic adsorption apparatus. The results manifested the pore features could be realized from the adsorption isotherm and hysteresis loop of nitrogen. In addition, as the percent of macropore volume was significant, the composite approach would be recommended as an alternative for analyzing pore features. The result of factor analysis implied the characteristic energy of adsorption was associated with the pore size distribution. It intended, except for physical adsorption, other mechanisms might coact on adsorption processes. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:237 / 247
页数:11
相关论文
共 15 条
[1]  
ADAMSON AW, 1982, PHYSICAL CHEM SURFAC
[2]   THE SURFACE-ACIDITY AND CHARACTERIZATION OF SOME COMMERCIAL ACTIVATED CARBONS [J].
CORAPCIOGLU, MO ;
HUANG, CP .
CARBON, 1987, 25 (04) :569-578
[3]  
deBoer J.H., 1958, STRUCTURE PROPERTIES
[4]  
GREGG SJ, 1967, ADSORPTION SURFACE A
[5]   METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].
HORVATH, G ;
KAWAZOE, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475
[6]  
Jankowska H., 1991, Active Carbon
[7]   STUDIES ON PORE SYSTEMS IN CATALYSTS .V. T METHOD [J].
LIPPENS, BC ;
DEBOER, JH .
JOURNAL OF CATALYSIS, 1965, 4 (03) :319-&
[8]   ADSORPTION AND STRUCTURE IN MICROPOROUS CARBONS [J].
MCENANEY, B .
CARBON, 1988, 26 (03) :267-274
[9]   INVESTIGATIONS OF A COMPLETE PORE STRUCTURE ANALYSIS .I. ANALYSIS OF MICROPORES [J].
MIKHAIL, RS ;
BRUNAUER, S ;
BODOR, EE .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1968, 26 (01) :45-&
[10]   CURVATURE AND PARAMETRIC SENSITIVITY IN MODELS FOR ADSORPTION IN MICROPORES [J].
SAITO, A ;
FOLEY, HC .
AICHE JOURNAL, 1991, 37 (03) :429-436