Covalently linked multi-calixarenes

被引：46

作者：

Mogck, O

Parzuchowski, P

Nissinen, M

Böhmer, V

Rokicki, G

Rissanen, K

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

[2] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

[3] Univ Jyvaskyla, Dept Chem, FIN-40351 Jyvaskyla, Finland

来源：

TETRAHEDRON | 1998年 / 54卷 / 34期

关键词：

D O I：

10.1016/S0040-4020(98)00594-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ipso-Nitration of t-butyl calix[4]arene tetraethers and subsequent hydrogenation provides an easy access to monoamino calix[4]arenes. Reaction with di- and triacid chlorides leads to various double- and triple-calix[4]arenes. With tetra-acid chlorides derived from calix[4]arenes in the cone- or 1,3-alternate-conformations penta-calix[4]arenes are available as molecularly uniform species, which may be regarded as the first generation of calix[4]arene based dendrimers. The structure of the mononitro tetraester derivative, which may serve as a general building block has been confirmed by single crystal X-ray analysis. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：10053 / 10068

页数：16

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