Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water

被引：41

作者：

Verdejo, B

Aguilar, J

Doménech, A

Miranda, C

Navarro, P

Jiménez, HR

Soriano, C

García-España, E

机构：

[1] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan & Organ, E-46100 Burjassot, Spain

[2] CSIC, Ctr Quim Organ Manuel Lora Tamayo, Inst Quim Med, Madrid 28006, Spain

[3] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Burjassot, Spain

[4] Univ Valencia, Fac Quim, Dept Quim Analit, E-46100 Burjassot, Spain

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 24期

关键词：

D O I：

10.1039/b503417e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

L-Glutamate and L-aspartate selectivity is achieved by the action of two Cu2+ metal ions rightly disposed in a cyclophane-type macrocyclic framework; electrochemical sensing of glutamate has been achieved by adsorption of the copper complexes on graphite electrodes.

引用

页码：3086 / 3088

页数：3

共 26 条

[1] Stability and kinetics of the acid-promoted decomposition of Cu(II) complexes with hexaazacyclophanes:: kinetic studies as a probe to detect changes in the coordination mode of the macrocycles [J].