(S,S)-trans-2,3-tetralindiol

被引:2
作者
Lloyd, MA [1 ]
Patterson, GE [1 ]
Brock, CP [1 ]
机构
[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
关键词
D O I
10.1107/S010827019800537X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Enantiomerically pure trans-2,3-tetralindiol [(R,R)- or (S,S)-trans-1,2,3, 4-tetrahydro-2, 3-naphthalenediol, C10H12O2] crystallizes in a layered structure, with two independent molecules in the asymmetric unit and an unbalanced arrangement of hydrogen bonds. The hydroxyl groups of one molecule form normal, if somewhat long, hydrogen bonds, but one of the O atoms in the other molecule accepts two protons while the second accepts none. The four O ... O distances range from 2.817(3) to 2.921 (3) Angstrom.
引用
收藏
页码:1486 / 1488
页数:3
相关论文
共 8 条
[1]  
BRIANSO MC, 1976, CR ACAD SCI C CHIM, V283, P457
[2]   ON THE VALIDITY OF WALLACH RULE - ON THE DENSITY AND STABILITY OF RACEMIC CRYSTALS COMPARED WITH THEIR CHIRAL COUNTERPARTS [J].
BROCK, CP ;
SCHWEIZER, WB ;
DUNITZ, JD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (26) :9811-9820
[3]  
*ENR NON, 1988, CAD 4 MAN VERS 5 0
[4]  
Jacques J., 1981, Enantiomers, Racemates and Resolutions
[5]   STRUCTURE OF CIS-2,3-TETRALINDIOL, CIS-1,2,3,4-TETRAHYDRO-2,3-NAPHTHALENEDIOL, C10H12O2 [J].
KLEIN, CL ;
MAJESTE, RJ ;
TSANG, WS ;
GRIFFIN, GW ;
STEVENS, ED .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (OCT) :1405-1407
[6]  
SHELDRICK GM, 1993, SHELXL93 PROGRAM REF
[7]  
SHELDRICK GM, 1990, SHELXTLIPC USERS MAN
[8]  
Verkade PE, 1928, LIEBIGS ANN CHEM, V467, P217