Ultralight, Soft Polymer Sponges by Self-Assembly of Short Electrospun Fibers in Colloidal Dispersions

被引:205
作者
Duan, Gaigai [1 ,2 ]
Jiang, Shaohua [1 ,2 ]
Jerome, Valerie [3 ]
Wendorff, Joachim H. [4 ]
Fathi, Amir [5 ]
Uhm, Jaqueline [5 ]
Altstaedt, Volker [5 ]
Herling, Markus [6 ]
Breu, Josef [6 ]
Freitag, Ruth [3 ]
Agarwal, Seema [1 ,2 ]
Greiner, Andreas [1 ,2 ]
机构
[1] Univ Bayreuth, Macromol Chem 2, D-95440 Bayreuth, Germany
[2] Univ Bayreuth, Bayreuth Ctr Colloids & Interfaces, D-95440 Bayreuth, Germany
[3] Univ Bayreuth, Proc Biotechnol, D-95440 Bayreuth, Germany
[4] Univ Marburg, Dept Chem, D-35032 Marburg, Germany
[5] Univ Bayreuth, Polymer Engn, D-95440 Bayreuth, Germany
[6] Univ Bayreuth, Inorgan Chem, D-95440 Bayreuth, Germany
关键词
MECHANICAL-PROPERTIES; FOAMS; AEROGELS; SCAFFOLDS; BEHAVIOR; DENSITY; WATER;
D O I
10.1002/adfm.201500001
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Ultralight polymer sponges are prepared by freeze-drying of dispersions of short electrospun fibers. In contrast to many other highly porous materials, these sponges show extremely low densities (<3 mg cm(-3)) in combination with low specific surface areas. The resulting hierarchical pore structure of the sponges gives basis for soft and reversibly compressible materials and to hydrophobic behavior in combination with excellent uptake for hydrophobic liquids. Owing to their large porosity, cell culturing is successful after hydrophilic modification of the sponges.
引用
收藏
页码:2850 / 2856
页数:7
相关论文
共 34 条
[1]
Functional materials by electrospinning of polymers [J].
Agarwal, Seema ;
Greiner, Andreas ;
Wendorff, Joachim H. .
PROGRESS IN POLYMER SCIENCE, 2013, 38 (06) :963-991
[2]
Skeleton of Euplectella sp.:: Structural hierarchy from the nanoscale to the macroscale [J].
Aizenberg, J ;
Weaver, JC ;
Thanawala, MS ;
Sundar, VC ;
Morse, DE ;
Fratzl, P .
SCIENCE, 2005, 309 (5732) :275-278
[3]
Compressive and tensile behaviour of aluminum foams [J].
Andrews, E ;
Sanders, W ;
Gibson, LJ .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 270 (02) :113-124
[4]
Modeling percolation in high-aspect-ratio fiber systems. I. Soft-core versus hard-core models [J].
Berhan, L. ;
Sastry, A. M. .
PHYSICAL REVIEW E, 2007, 75 (04)
[5]
Mechanical properties of highly porous PDLLA/Bioglass® composite foams as scaffolds for bone tissue engineering [J].
Blaker, JJ ;
Maquet, V ;
Jérôme, R ;
Boccaccini, AR ;
Nazhat, SN .
ACTA BIOMATERIALIA, 2005, 1 (06) :643-652
[6]
Light inside sponges [J].
Bruemmer, Franz ;
Pfannkuchen, Martin ;
Baltz, Alexander ;
Hauser, Thomas ;
Thiel, Vera .
JOURNAL OF EXPERIMENTAL MARINE BIOLOGY AND ECOLOGY, 2008, 367 (02) :61-64
[7]
Mechanical properties of tannin-based rigid foams undergoing compression [J].
Celzard, A. ;
Zhao, W. ;
Pizzi, A. ;
Fierro, V. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (16-17) :4438-4446
[8]
Chen H. H., 1965, POLYM ENG SCI, V5, P90
[9]
Colombo P, 2001, J AM CERAM SOC, V84, P2245, DOI 10.1111/j.1151-2916.2001.tb00996.x
[10]
Statistical geometry of pores and statistics of porous nanofibrous assemblies [J].
Eichhorn, SJ ;
Sampson, WW .
JOURNAL OF THE ROYAL SOCIETY INTERFACE, 2005, 2 (04) :309-318