Meta-Terphenyl Derivative/ Iodonium Salt/9H-Carbazole-9-ethanol Photoinitiating Systems for Free Radical Promoted Cationic Polymerization upon Visible Lights

被引：43

作者：

Al Mousawi, Assi ^{[1
,2
]}

Dietlin, Celine ^{[1
]}

Graff, Bernadette ^{[1
]}

Morlet-Savary, Fabrice ^{[1
]}

Toufaily, Joumana ^{[2
,3
]}

Hamieh, Tayssir ^{[2
]}

Fouassier, Jean Pierre ^{[1
]}

Chachaj-Brekiesz, Anna ^{[4
]}

Ortyl, Joanna ^{[5
,6
]}

Lalevee, Jacques ^{[1
]}

机构：

[1] UHA, CNRS, UMR 7361, IS2M, 15 Rue Jean Starcky, F-68057 Mulhouse, France

[2] Univ Libanaise, EDST, Lab Mat Catalyse Environm & Methodes Analyt MCEMA, Campus Hariri, Hadath, Beyrouth, Lebanon

[3] Univ Libanaise, EDST, LEADDER, Campus Hariri, Hadath, Beyrouth, Lebanon

[4] Jagiellonian Univ, Fac Chem, Ingardena 3, PL-30060 Krakow, Poland

[5] Cracow Univ Technol, Fac Chem Engn & Technol, Warszawska 24, PL-31155 Krakow, Poland

[6] Photo HiTech Ltd, Bobrzynskiego 14, PL-30348 Krakow, Poland

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2016年 / 217卷 / 17期

关键词：

additives; cationic polymerization; free radical promoted cationic polymerization; light emitting diodes (LEDs); visible light; PHOTOPOLYMERIZATION; SALT; PHOTOSENSITIZERS; ACCELERATION; ELECTRON; KINETICS;

D O I：

10.1002/macp.201600224

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

In the present paper, new photoinitiators based on the meta-terphenyl scaffold in combination with an iodonium salt and 9H-carbazole-9-ethanol (CARET) are proposed for the free radical promoted cationic polymerization of epoxides upon visible light exposure using light emitting diodes at 405, 455, and 470 nm. Remarkably, a new high performance additive (i.e., CARET) is proposed here for cationic polymerizations. CARET shows some important advantages compared to other reported additives such as N-vinylcarbazole or benzyl alcohol used as references. Excellent polymerization initiating abilities are found and a full picture of the involved chemical mechanisms is provided.

引用

页码：1955 / 1965

页数：11

共 37 条

[1]

[Anonymous], 1999, EXPLORING SCI TECHNO

[2]

A dithienothiophene derivative as a long-wavelength photosensitizer for onium salt photoinitiated cationic polymerization [J].

Aydogan, Binnur ;

Gundogan, Ali Senol ;

Ozturk, Turan ;

Yagci, Yusuf .

MACROMOLECULES, 2008, 41 (10) :3468-3471

[3]

Highly Conjugated Thiophene Derivatives as New Visible Light Sensitive Photoinitiators for Cationic Polymerization [J].

Aydogan, Binnur ;

Gunbas, Gorkem E. ;

Durmus, Asuman ;

Toppare, Levent ;

Yagci, Yusuf .

MACROMOLECULES, 2010, 43 (01) :101-106

[4]

Belfied K. D., 2003, ACS S SERIES, V847

[5]

A synergistic effect of a ferrocenium salt on the diaryliodonium salt-induced visible-light curing of bisphenol-A epoxy resin [J].

Chen, Yu ;

Jia, Xiaoqin ;

Wang, Mengqiang ;

Wang, Tao .

RSC ADVANCES, 2015, 5 (42) :33171-33176

[6]

Photo-curing kinetics for the UV-initiated cationic polymerization of a cycloaliphatic diepoxide system photosensitized by thioxanthone [J].

Cho, JD ;

Hong, JW .

EUROPEAN POLYMER JOURNAL, 2005, 41 (02) :367-374

[7]

Long wavelength photosensitizers in photoinitiated cationic polymerization: The effect of quinoxaline derivatives on photopolymerization [J].

Corakci, Bengisu ;

Hacioglu, Serife O. ;

Toppare, Levent ;

Bulut, Umut .

POLYMER, 2013, 54 (13) :3182-3187

[8]

Crivello J. V., 2012, POLYM SCI COMPREHENS, P919

[9]

Crivello J, 2015, DYES AND CHROMOPHORES IN POLYMER SCIENCE, P45

[10]

Anthracene electron-transfer photosensitizers for onium salt induced cationic photopolymerizations [J].

Crivello, JV ;

Jang, M .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 159 (02) :173-188

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