Conductivity studies on aqueous solutions of stereoisomers of tartaric acids and tartrates. Part III. Acidic tartrates

被引:20
作者
Bester-Rogac, M
Neueder, R
Barthel, J
Apelblat, A
机构
[1] Univ Regensburg, Inst Phys & Theoret Chem, D-93040 Regensburg, Germany
[2] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel
关键词
temperature dependence of conductivity; ion conductivities; aqueous solutions; sodium hydrogen tartrate; potassium hydrogen tartrate;
D O I
10.1023/A:1022671414577
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Conductivity measurements on aqueous solutions of sodium hydrogen tartrate and potassium hydrogen tartrate were performed in the temperature range 5-35 degrees C. By including the dissociation equilibria, the experimental conductivities of the acidic salts can be well described using equivalent limiting conductivities of the bitartrate anion lambda(infinity)(HTar(-)) and the tartrate anion lambda(infinity) (1/2 Tar(2-)) when applying the Quint and Viallard equations for unsymmetrical electrolytes.
引用
收藏
页码:299 / 307
页数:9
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